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ChemicalBook--->CAS DataBase List--->5735-41-1

5735-41-1

5735-41-1 Structure

5735-41-1 Structure
IdentificationMore
[Name]

1-Hydroxy-2,1-benzoxaborolane
[CAS]

5735-41-1
[Synonyms]

1-HYDROXY-2,1-BENZOXABOROLANE
2-(HYDROXYMETHYL)BENZENEBORONIC ACID CYCLIC MONOESTER
(2-HYDROXYMETHYL)BENZENEBORONIC ACID DEHYDRATE
2-(HYDROXYMETHYL)BENZENEBORONIC ACID HEMIESTER
2-(HYDROXYMETHYL)PHENYLBORONIC ACID CYCLIC MONOESTER
(2-HYDROXYMETHYLPHENYL)BORONIC ACID DEHYDRATE
2-(HYDROXYMETHYL)PHENYLBORONIC ACID, DIHYDRATE
AKOS BRN-0113
1-Hydroxy-2,1-benzoxaborolane~2-(Hydroxymethyl)phenylboronic acid cyclic monoester
2-(HYDROXYMETHYL)PHENYLBORONIC ACID CYC&
1-Hydroxy-1,2-benzoxaborolane
2-(Hydroxymethyl)Phenylboronic
2-(Hydroxymethyl)benzeneboronic acid dehydrate 98%
1-Hydroxy-2,1-benzoxaborolane, Alt cas [87199-14-2]
2-Hydroxymethylphenylboronic acid, dehydrated
2-(HYDROXYMETHYL)BENZENEBORONIC ACID HEMIESTER, 98+%
1,3-Dihydro-1-hydroxy-2,1-benzoxaborole, 2-(Hydroxymethyl)phenylboronic acid hemiester
[Molecular Formula]

C7H7BO2
[MDL Number]

MFCD01075677
[Molecular Weight]

133.94
[MOL File]

5735-41-1.mol
Chemical PropertiesBack Directory
[Melting point ]

95-100 °C
[Boiling point ]

237.2±43.0 °C(Predicted)
[density ]

1.18±0.1 g/cm3(Predicted)
[storage temp. ]

Keep Cold
[form ]

powder to crystal
[pka]

7.01±0.20(Predicted)
[color ]

White to Almost white
[BRN ]

4333
[CAS DataBase Reference]

5735-41-1(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[Hazard Note ]

Irritant/Keep Cold
[HS Code ]

29349990
Hazard InformationBack Directory
[Chemical Properties]

Solid
[Uses]

Oxaboroles and benzoxaboroles are useful substrates to prepare allylic and benzylic alcohols via Suzuki coupling.
[Definition]

ChEBI: 1-hydroxy-2,1-benzoxaborole is a member of the class of benzoxaboroles that is 2,1-benzoxaborole in which the hydrogen attached to the boron atom is replaced by a hydroxy group.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 80, p. 835, 1958 DOI: 10.1021/ja01537a021
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

2-(Hydroxymethyl)benzeneboronic acid hemiester, 98+%(5735-41-1)
[Sigma Aldrich]

5735-41-1(sigmaaldrich)
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