| Identification | More | [Name]
3-Chloro-1-butene | [CAS]
563-52-0 | [Synonyms]
1-methylallyl chloride
3-CHLORO-1-BUTENE
ALPHA-METHALLYL CHLORIDE
(±)-3-chloro-but-1-ene
1-butene,3-chloro-
2-Chloro-3-butene
3-Chlor-1-buten
3-chloro-1-buten
3-chlorobut-1-ene
alpha-Methylallyl chloride
alpha-methylallylchloride
dl-α-Methallylchloride
gamma-Chloro-alpha-butylene
α-Methyl-allylchlorid
1-Methyl-1-chloro-2-propene
a-Methallyl chloride
a-Methylallyl chloride
g-Chloro-a-butylene
1-Methyl-2-propenyl chloride | [EINECS(EC#)]
209-252-8 | [Molecular Formula]
C4H7Cl | [MDL Number]
MFCD00000869 | [Molecular Weight]
90.55 | [MOL File]
563-52-0.mol |
| Safety Data | Back Directory | [Hazard Codes ]
F,Xi,Xn | [Risk Statements ]
R11:Highly Flammable.
R43:May cause sensitization by skin contact.
R36/37/38:Irritating to eyes, respiratory system and skin .
R22:Harmful if swallowed. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S36/37:Wear suitable protective clothing and gloves .
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
UN 1993 3/PG 2
| [WGK Germany ]
2
| [RTECS ]
EM4261000
| [F ]
8-19 | [HazardClass ]
3.1 | [PackingGroup ]
II | [HS Code ]
29032990 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless liquid | [Uses]
3-Chloro-1-butene is used as a alkylating agent and organometallic precursor useful for introduction of 2-buten-1-yl (crotyl) and 1-buten-3- yl moieties).
| [Preparation]
3-Chloro-1-butene is prepared from 1-buten-3-ol using PCl3/py, SOCl2/HMPA, Ph3P/CCl4, Ph3P/CCl3COCCl, Me2CC(Cl)NMe or PO(OPh)2Cl/LiCl; from 2-buten-1-ol using SOCl2/FeCl3.
| [Precautions]
3-Chloro-1-butene is stable at 0°C in quartz; flammable liquid and lachrymator. Use in a fume hood.
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