Identification | More | [Name]
2-IODO-2-METHYLPROPANE | [CAS]
558-17-8 | [Synonyms]
2-IODO-2-METHYLPROPANE T-BUTYL IODIDE TERT-BUTYL IODIDE Trimethyliodomethane 2-iodo-2-methyl-propan 2-Jod-2-methylpropan 2-methyl-2-iodopropane Propane, 2-iodo-2-methyl- propane,2-iodo-2-methyl- tert.-Butyljodid tert-C4H9I 2-Iodo-2-methylpropane, stabilized, 95% 2-Iodo-2-methylpropane, GC 95% 2-IODO-2-METHYLPROPANE , STABILIZED WITH COPPER POWDER TERT-BUTYL IODIDE (STABILIZED WITH COPPER CHIP) 2-Iodo-2-methylpropane, 95%, stab. with copper powder 2-Iodo-2-methylpropane (stabilized with Copper chip) 2-Iodo-2-methylpropane, 97%, stab. with copper powder 2-Iodo-2-methylpropane, 95%, stabilized 1-Iodo-1,1-dimethylethane | [EINECS(EC#)]
209-190-1 | [Molecular Formula]
C4H9I | [MDL Number]
MFCD00001068 | [Molecular Weight]
184.02 | [MOL File]
558-17-8.mol |
Chemical Properties | Back Directory | [Appearance]
deep brown liquid | [Melting point ]
−38 °C(lit.) | [Boiling point ]
99-100 °C(lit.) | [density ]
1.544 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.491(lit.)
| [Fp ]
46 °F
| [storage temp. ]
2-8°C
| [solubility ]
Miscible with ethanol and ether. | [form ]
clear liquid to cloudy liquid | [color ]
Colorless to Light yellow to Light orange | [Stability:]
Stable, but may discolour upon exposure to light. Highly flammable. Incompatible with strong bases, strong oxidizing agents. | [Sensitive ]
Light Sensitive | [BRN ]
505950 | [Dielectric constant]
8.4199999999999999 | [CAS DataBase Reference]
558-17-8(CAS DataBase Reference) | [EPA Substance Registry System]
Propane, 2-iodo-2-methyl- (558-17-8) |
Safety Data | Back Directory | [Hazard Codes ]
F,Xi | [Risk Statements ]
R11:Highly Flammable. R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . | [RIDADR ]
UN 2391 3/PG 2
| [WGK Germany ]
3
| [RTECS ]
TZ4251000
| [F ]
8-10-23 | [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29033990 |
Hazard Information | Back Directory | [Chemical Properties]
deep brown liquid | [Uses]
2-Iodo-2-methylpropane is used as a chemical reagent in organic synthesis. Further, it serves as a pharmaceutical intermediate. | [Synthesis Reference(s)]
Tetrahedron Letters, 36, p. 609, 1995 DOI: 10.1016/0040-4039(94)02315-3 | [General Description]
2-Iodo-2-methylpropane was degraded by reductive dehalogenation with nickel-aluminum alloy in potassium hydroxide solution. | [Purification Methods]
Vacuum distillation has been used to obtain a distillate which remained colourless for several weeks at -5o. More extensive treatment has been used by Boggs, Thompson and Crain [J Phys Chem 61 625 1957] who washed with aqueous NaHSO3 solution to remove free iodine, dried this for 1hour over Na2SO3 at 0o, and purified it by four or five successive partial freezings of the liquid to obtain colourless material and was stored at -78o with Ag wool. [Beilstein 1 IV 300.] |
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Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
Company Name: |
Energy Chemical
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Tel: |
021-021-58432009 400-005-6266 |
Website: |
http://www.energy-chemical.com |
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