| Identification | More | [Name]
ALLYL IODIDE | [CAS]
556-56-9 | [Synonyms]
3-IODO-1-PROPENE
3-IODOPROPENE
3-IODOPROPYLENE
ALLYL IODIDE
1-propene,3-iodo-
2-Propene, 1-iodo
2-Propenyliodide
3-iodo-1-propen
3-iodo-prop-1-ene
3-iodo-propen
3-Iodpropen
3-Jod-1-propen
3-Jodpropen
Allyliodid
Allyljodid
CH2CHCH2I
Propene, 3-iodo-
propene,3-iodo-
Allyl iodide
3-Iodopropene
ALLYL IODIDE, STAB. | [EINECS(EC#)]
209-130-4 | [Molecular Formula]
C3H5I | [MDL Number]
MFCD00001094 | [Molecular Weight]
167.98 | [MOL File]
556-56-9.mol |
| Chemical Properties | Back Directory | [Appearance]
clear orange, red or red-brown liquid | [Melting point ]
-99 °C
| [Boiling point ]
102103°C
| [density ]
1.837 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.554
| [Fp ]
65 °F
| [storage temp. ]
2-8°C
| [solubility ]
alcohol: miscible(lit.) | [form ]
Liquid | [color ]
Clear yellow to orange, red or red-brown | [Water Solubility ]
Soluble in alcohol, chloroform, ether, and diethyl ether. Insoluble in water. | [Sensitive ]
Air & Light Sensitive | [Merck ]
14,294 | [BRN ]
1697594 | [Dielectric constant]
6.1（19℃） | [Exposure limits]
ACGIH: TWA 0.01 ppm | [InChIKey]
HFEHLDPGIKPNKL-UHFFFAOYSA-N | [CAS DataBase Reference]
556-56-9(CAS DataBase Reference) | [EPA Substance Registry System]
1-Propene, 3-iodo- (556-56-9) |
| Safety Data | Back Directory | [Hazard Codes ]
C,T,F | [Risk Statements ]
R10:Flammable.
R34:Causes burns. | [Safety Statements ]
S7:Keep container tightly closed .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 1723 3/PG 2
| [WGK Germany ]
1
| [RTECS ]
UD0450000
| [F ]
8-13 | [TSCA ]
T | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29033990 | [Safety Profile]
Poison by inhalation and ingestion. Mutation data reported. A powerful irritant. A flammable liquid. Incompatible with oxidizing materials. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits hghly toxic fumes of I-. See also ALLYL COMPOUNDS and IODIDES. |
| Hazard Information | Back Directory | [General Description]
A yellow liquid with a pungent odor. Denser than water and insoluble in water. Hence sinks in water. Vapors are heavier than air. Flash point is less than 75°F. Very irritating to skin, eyes and mucous membranes. Poisonous by ingestion and inhalation. Used to make other chemicals. | [Reactivity Profile]
ALLYL IODIDE(556-56-9) is moderately reactive. Incompatible with strong oxidizing and reducing agents. Also, incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. | [Air & Water Reactions]
Highly flammable. Darkens on exposure to light and air liberating Iodine [Merck 11th ed. 1989]. Insoluble in water. | [Health Hazard]
May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. | [Fire Hazard]
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. | [Chemical Properties]
clear orange, red or red-brown liquid | [Uses]
Allyl iodide is used as a reagent used with allylindium sesquiiodide in the cis-double allylation of cyclopropenes. It is used in synthesis of other organic compounds such as N-alkyl 2-pyrrolidone, Sorbic acid ester etc,. | [Synthesis Reference(s)]
Synthetic Communications, 20, p. 41, 1990 DOI: 10.1080/00397919008054613 | [Purification Methods]
Purify allyl iodide in a dark room by washing with aqueous Na2SO3 to remove free iodine, then dry with MgSO4 and distil at 43o/90 mm or at atmospheric pressure to give a very pale yellow liquid. (This material, dissolved in hexane, can be stored in a light-protected tight container at -5o for up to three months before free iodine could be detected, by its colour in the solution.) Store it away from light. [Sibbett & Noyes J Am Chem Soc 75 761 1953, Beilstein 1 H 202, 1 I 84, 1 II 172, 1 III 714, 1 IV 761.] |
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