| Identification | More | [Name]
ALUMINUM ETHOXIDE | [CAS]
555-75-9 | [Synonyms]
ALUMINIUM ETHOXIDE
ALUMINIUM ETHYLATE
ALUMINIUM TRIETHANOLATE
ALUMINIUM TRIETHOXIDE
ALUMINIUM TRIETHYLATE
ALUMINUM ETHOXIDE
ALUMINUM(III) ETHOXIDE
ALUMINUM TRIETHOXIDE
Aluminum tri(ethanolate)
aluminumethylate
aluminumtriethoxyde
Ethanol, aluminum salt
ethanol,aluminumsalt
ethylalcohol,aluminumsalt
triethoxyaluminum
Aliuminum ethylate
ALUMINUM TRIETHYLATE
Aluminumethoxide,99%
Tris(ethoxy) aluminum | [EINECS(EC#)]
209-105-8 | [Molecular Formula]
C6H15AlO3 | [MDL Number]
MFCD00009658 | [Molecular Weight]
162.16 | [MOL File]
555-75-9.mol |
| Chemical Properties | Back Directory | [Appearance]
white powder | [Melting point ]
154-159 °C (lit.) | [Boiling point ]
320 °C | [density ]
1,142 g/cm3 | [vapor pressure ]
0.004Pa at 25℃ | [Fp ]
210°C/10mm | [storage temp. ]
Store below +30°C. | [solubility ]
reacts with H2O; slightly soluble in xylene | [form ]
Powder/Chunks | [color ]
White | [Specific Gravity]
1.142 | [Water Solubility ]
Soluble in hot xylene, cholorobenzene. Reacts with water. | [Hydrolytic Sensitivity]
8: reacts rapidly with moisture, water, protic solvents | [Sensitive ]
Moisture Sensitive | [Merck ]
14,338 | [BRN ]
3678970 | [CAS DataBase Reference]
555-75-9(CAS DataBase Reference) | [EPA Substance Registry System]
Aluminum ethoxide (555-75-9) |
| Safety Data | Back Directory | [Hazard Codes ]
F,C | [Risk Statements ]
R11:Highly Flammable.
R15:Contact with water liberates extremely flammable gases.
R34:Causes burns. | [Safety Statements ]
S8:Keep container dry .
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 1325 4.1/PG 2
| [WGK Germany ]
3
| [F ]
3-10-23 | [TSCA ]
Yes | [HS Code ]
2905 19 00 | [HazardClass ]
4.1 | [PackingGroup ]
II | [Hazardous Substances Data]
555-75-9(Hazardous Substances Data) |
| Hazard Information | Back Directory | [Chemical Properties]
liquid that slowly solidifies to a white powder(s); sensitive to moisture; prepared from a reaction of Al with ethanol in the presence of catalytic amounts of I2 and HgCl2; used as a polymerization catalyst and to reduce aldehydes and ketones [MER06] [STR93] [HAW93] | [Uses]
Aluminum ethoxide is mainly used in industrial settings. It is used as a reducing agent for aldehyde, ketones, polymerization catalyst. Used in the sol-gel process preparation of high purity aluminum sesquioxide. It also used as a reducing reagent, for carbonyl compounds that restore to alcohol. | [Uses]
In the reduction of aldehydes and ketones; as catalyst for polymerizations. | [Flammability and Explosibility]
Flammable | [Purification Methods]
Crystallise it from CS2 [m 139o, CS2 complex] and distil it in a vacuum. The molecular weight corresponds to [Al(OEt)3]4 [Robinson & Peak J Phys Chem 39 1127 1935, Vilani & Nord J Am Chem Soc 69 2605 1947]. [Beilstein 1 H 313, 1 I 158, 1 II 3008, 1 III 1284, 1 IV 1289.] |
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