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ChemicalBook--->CAS DataBase List--->543-39-5

543-39-5

543-39-5 Structure

543-39-5 Structure
IdentificationBack Directory
[Name]

7-OCTEN-2-OL, 2-METHYL-6-METHYLENE
[CAS]

543-39-5
[Synonyms]

MYCENOL5
MYRCENOL
2H MYRCENOL
MYRCENOL 50
MYRCENOL 50 IN D.E.P.
2-Methyl-6-methylenoct-7-en-2-ol
2-methyl-6-methylene-7-octen-2-o
2-Methyl-6-methylene-7-octen-2-ol
3-Methylene-7-methyl-1-octen-7-ol
2-methyl-6-methyleneoct-7-en-2-ol
7-OCTEN-2-OL, 2-METHYL-6-METHYLENE
2-methyl-6-methylideneoct-7-en-2-ol
2-methyl-6-methylidene-oct-7-en-2-ol
[EINECS(EC#)]

208-843-8
[Molecular Formula]

C10H18O
[MDL Number]

MFCD00128271
[MOL File]

543-39-5.mol
[Molecular Weight]

154.25
Chemical PropertiesBack Directory
[Boiling point ]

217.64°C (rough estimate)
[density ]

0.8389 (rough estimate)
[refractive index ]

1.4666 (estimate)
[solubility ]

Practically insoluble in water, soluble in alcohol and oils.
[form ]

viscous liquid
[pka]

15.30±0.29(Predicted)
[color ]

Colorless
[Specific Gravity]

0.89
[Odor]

at 100.00 %. fresh floral lavender citrus
[Odor Type]

floral
[Stability:]

Tends to polymerize on standing, increases in viscosity, decreases in odor power
[LogP]

2.613 (est)
[EPA Substance Registry System]

7-Octen-2-ol, 2-methyl-6-methylene- (543-39-5)
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
Hazard InformationBack Directory
[Chemical Properties]

It is a colorless liquid with a fresh, floral, slightly lime-like odor. Due to its conjugated double bonds, it tends to polymerize; polymerization can be suppressed by adding inhibitors (e.g., antioxidants such as BHT).
Myrcenol can be prepared by treating myrcene with diethylamine to give a mixture of geranyl- and neryldiethylamine. These compounds are hydrated with a dilute acid to the corresponding hydroxydiethylamines. Deamination tomyrcenol is effected by using a palladium–phosphine–cation complex as a catalyst.
Myrcenol is used in perfumery to obtain a lifting top note in citrus and lavender compositions. It is mainly important in the production of 4-(4-hydroxy-4- methylpentyl)-3-cyclohexenecarboxaldehyde.
[Uses]

Myrcenol is used in perfume compositions for “l(fā)ift” and freshness in floral or citrusy and “l(fā)ight” compositions, including soap perfumes.
[Definition]

ChEBI: A monoterpenoid that is oct-7-en-2-ol substituted by a methyl group at position 2 and a methylidene group at position 6 respectively.
[Preparation]

By chlorination of Myrcene, followed by hydrolysis.
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