| Identification | More | [Name]
3-OXO-3-O-TOLYL-PROPIONIC ACID ETHYL ESTER | [CAS]
51725-82-7 | [Synonyms]
Ethyl o-toluoylacetate
3-OXO-3-O-TOLYLPROPANOATE
Ethyl o-methylbenzoylacetate
ETHYL (2-METHYLBENZOYL)ACETATE
ETHYL 3-OXO-3-O-TOLYLPROPANOATE
Ethyl 2-(2-methylbenzoyl)acetate
Ethyl 3-Oxo-3-(o-tolyl)propionate
Ethyl (2-methylbenzoyl)acetate 97%
2-Methylbenzoylacetic acid ethyl ester
2-[(2-methylphenyl)-oxomethyl]butanoate
3-OXO-3-O-TOLYL-PROPIONIC ACID ETHYL ESTER
3-OXO-3-(2-TOLYL)PROPIONIC ACID ETHYL ESTER
β-Oxo-2-methylbenzenepropionic acid ethyl ester
Benzenepropanoicacid,2-methyl-β-oxo-,ethylester
3-(2-Methylphenyl)-3-oxopropionic acid ethyl ester
3-Oxo-3-(2-methylphenyl)propanoic acid ethyl ester
3-Oxo-3-(2-methylphenyl)propionic acid ethyl ester
Benzenepropanoic acid, 2-methyl-β-oxo-, ethyl ester | [Molecular Formula]
C12H14O3 | [MDL Number]
MFCD03424817 | [Molecular Weight]
206.24 | [MOL File]
51725-82-7.mol |
| Chemical Properties | Back Directory | [Boiling point ]
256-257 °C(lit.) | [density ]
1.069 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.5255(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [form ]
clear liquid | [pka]
10.00±0.46(Predicted) | [color ]
Colorless to Light yellow to Light orange | [λmax]
287nm(MeOH)(lit.) | [CAS DataBase Reference]
51725-82-7(CAS DataBase Reference) |
| Hazard Information | Back Directory | [Uses]
Reactant for:
- Preparation of highly substituted furans by tandem condensation-cyclization reactions using bismuth triflate catalyst
- Co/Mn-mediated oxidative cross-coupling
- Enantioselective ruthenium-catalyzed hydrogenation
- Preparation of cambinol analogs for sirtuin inhibition with antitumor action
| [Uses]
Reactant for:• ;Preparation of highly substituted furans by tandem condensation-cyclization reactions using bismuth triflate catalyst1• ;Co/Mn-mediated oxidative cross-coupling2• ;Enantioselective ruthenium-catalyzed hydrogenation3• ;Preparation of cambinol analogs for sirtuin inhibition with antitumor action4 | [General Description]
Ethyl (2-methylbenzoyl)acetate is a β-keto ester. It undergoes Co/Mn mediated oxidative coupling reaction with various indole derivatives. |
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