| Identification | More | [Name]
(S)-(+)-1-(2-Pyrrolidinylmethyl)pyrrolidine | [CAS]
51207-66-0 | [Synonyms]
(S)-(-)-1-(2-PYRROLIDINYLMETHYL)PIPERIDINE
(S)-(+)-1-(2-PYRROLIDINYLMETHYL)PYRROLIDINE
(S)-(-)-1-METHYL-2-(1-PIPERIDINOMETHYL)PYRROLIDINE
(S)-1-METHYL-2-(PIPERIDINOMETHYL)PYRROLIDINE
(S)-(+)-1-(2-PYRROLIDINYLMETHYL)PYRROLIDINE 98+%
1-[(2S)-pyrrolidin-2-ylmethyl]pyrrolidine | [Molecular Formula]
C9H18N2 | [MDL Number]
MFCD00077821 | [Molecular Weight]
154.25 | [MOL File]
51207-66-0.mol |
| Chemical Properties | Back Directory | [Boiling point ]
99-101 °C2 mm Hg(lit.) | [density ]
0.946 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.4871(lit.)
| [Fp ]
220 °F
| [form ]
clear liquid | [pka]
10.91±0.10(Predicted) | [color ]
Colorless to Light yellow | [optical activity]
[α]19/D +7.0°, c = 2.4 in ethanol | [InChIKey]
YLBWRMSQRFEIEB-VIFPVBQESA-N | [CAS DataBase Reference]
51207-66-0(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/38:Irritating to eyes and skin .
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
NA 1993 / PGIII | [WGK Germany ]
3
| [F ]
10-34 | [HS Code ]
29339900 |
| Hazard Information | Back Directory | [Chemical Properties]
Liquid | [Uses]
(S)-(+)-1-(2-Pyrrolidinylmethyl)pyrrolidine can be used as an organocatalyst in the asymmetric synthesis of different optically active organic building blocks via Aldol condensation and Mannich reactions . It is also used as a catalyst to prepare enantioselective Michael adducts by reacting alkylidene malonates with unactivated ketones. |
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