Identification | More | [Name]
CIS-DECAHYDRONAPHTHALENE | [CAS]
493-01-6 | [Synonyms]
CIS-DECAHYDRONAPHTHALENE CIS-DECALIN CIS-NAPHTHALANE CIS-PERHYDRONAPHTHALENE c-Decahydronaphthalene c-Decalin cis-Bicyclo[4.4.0]Decane cis-decahydronaphthalenen cis-Decahydronapthalene cis-naphthalen decahydronaphthalene(cis-) decahydronaphthalene, cis cis-decaline CIS-DECAHYDRONAPHTHALENE OEKANAL, 250 MG cis-Decahydronaphthalene,99% Naphthalene, decahydro-, cis- cis-dekalin cis-Decahydronaphthalene [Standard Material] Decahydronaphthalene, cis-: (cis-Decalin) cis-Decalin(R) | [EINECS(EC#)]
207-770-9 | [Molecular Formula]
C10H18 | [MDL Number]
MFCD00064189 | [Molecular Weight]
138.25 | [MOL File]
493-01-6.mol |
Chemical Properties | Back Directory | [Appearance]
colourless liquid | [Melting point ]
−43 °C(lit.)
| [Boiling point ]
193 °C(lit.)
| [density ]
0.897 g/mL at 25 °C(lit.)
| [vapor density ]
4.76 (vs air)
| [vapor pressure ]
42 mm Hg ( 92 °C)
| [refractive index ]
n20/D 1.481(lit.)
| [Fp ]
137 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [form ]
clear liquid | [color ]
Colorless to Almost colorless | [Stability:]
Stable. Incompatible with oxidizing agents. May form explosive peroxides. Heat and light accelerate peroxide formation. | [explosive limit]
0.7-4.9%, 100°F | [Water Solubility ]
8.92g/L(300 ºC) | [Merck ]
2846 | [BRN ]
1900822 | [Dielectric constant]
2.2(20℃) | [CAS DataBase Reference]
493-01-6(CAS DataBase Reference) | [EPA Substance Registry System]
cis-Decahydronaphthalene (493-01-6) |
Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R20:Harmful by inhalation. R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . | [RIDADR ]
UN 1147 3/PG 3
| [WGK Germany ]
3
| [RTECS ]
QJ3150000 | [Autoignition Temperature]
482 °F | [HazardClass ]
3.2 | [PackingGroup ]
III | [HS Code ]
29021990 |
Hazard Information | Back Directory | [Chemical Properties]
colourless liquid | [Uses]
cis-Decahydronaphthalene is used as a quantitation standard in the determination of sesquiterpanes. | [Definition]
ChEBI: Decalin is an ortho-fused bicyclic hydrocarbon that is the decahydro- derivative of naphthalene. It has a role as a solvent. | [Purification Methods]
Purification methods described for the mixed isomers are applicable here. The individual isomers can be separated by very efficient fractional distillation, followed by fractional crystallisation by partial freezing. The cis-isomer reacts preferentially with AlCl3 and can be removed from the trans-isomer by stirring the mixture with a limited amount of AlCl3 for 48hours at room temperature, filtering and distilling. [Seyer & Walker J Am Chem Soc 60 2125 1938, Baker & Schuetz J Am Chem Soc 69 1250 1949.] A very pure authentic sample is best obtained by synthesis from cis-1,2-bis-chloroethylcyclohexane [Whitesides & Gutowski J Org Chem 41 2882 1976, Beilstein 5 IV 310.] |
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