| Identification | More | [Name]
TRIS(2-METHOXYPHENYL)PHOSPHINE | [CAS]
4731-65-1 | [Synonyms]
TRI(2-METHOXYPHENYL)PHOSPHINE
TRIS(2-METHOXYPHENYL)PHOSPHINE
TRIS(O-ANISYL)PHOSPHINE
TRIS(O-METHOXYPHENYL)PHOSPHINE
Phosphine, tris(2-methoxyphenyl)-
Tri(o-anisyl)phosphine
TRIS-(2-ANISYL)PHOSPHINE
Tris(o-methoxyphenyl)phosphine,min.98%
Tris(o-methoxyphenyl)phosphine, min. 98% | [EINECS(EC#)]
225-235-8 | [Molecular Formula]
C21H21O3P | [MDL Number]
MFCD00014892 | [Molecular Weight]
352.36 | [MOL File]
4731-65-1.mol |
| Chemical Properties | Back Directory | [Appearance]
white powder or crystals | [Melting point ]
204-208 °C
| [Boiling point ]
477.3±40.0 °C(Predicted) | [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
Liquid | [color ]
Colorless to yellow or pale orange | [Water Solubility ]
Slightly soluble in water. | [Sensitive ]
Air Sensitive | [BRN ]
2776186 | [InChI]
InChI=1S/C21H21O3P/c1-22-16-10-4-7-13-19(16)25(20-14-8-5-11-17(20)23-2)21-15-9-6-12-18(21)24-3/h4-15H,1-3H3 | [InChIKey]
IIOSDXGZLBPOHD-UHFFFAOYSA-N | [SMILES]
P(C1=CC=CC=C1OC)(C1=CC=CC=C1OC)C1=CC=CC=C1OC | [CAS DataBase Reference]
4731-65-1(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R22:Harmful if swallowed. | [Safety Statements ]
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
3 | [TSCA ]
No | [HS Code ]
29319090 |
| Hazard Information | Back Directory | [Chemical Properties]
white powder or crystals | [Uses]
suzuki reaction | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand | [References]
[1] Raymond C. Bott, Graham Smith, Peter C. Healy. “Structural studies of two-coordinate complexes of tris(2-methoxylphenyl)phosphine and tris(4-methoxyphenyl)phosphine with gold(I) halides.” Polyhedron 26 12 (2007): Pages 2803-2809.
[2] O. Shawkataly. “Pentacarbonyl[tris(2-methoxyphenyl)phosphine-P]chromium and its Molybdenum Analogue.” Acta crystallographica. Section C, Crystal structure communications 75 1 (1996): 1352–1355.
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