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ChemicalBook--->CAS DataBase List--->4551-15-9

4551-15-9

4551-15-9 Structure

4551-15-9 Structure
IdentificationMore
[Name]

PHENYLTHIOTRIMETHYLSILANE
[CAS]

4551-15-9
[Synonyms]

PHENYLTHIOTRIMETHYLSILANE
PHENYL TRIMETHYLSILYL SULFIDE
S-(TRIMETHYLSILYL)BENZENETHIOL
S-(TRIMETHYLSILYL)THIOPHENOL
TRIMETHYL(PHENYLTHIO)SILANE
Phenylthiotrimethylsilane(S-Trimethylsilylthiophenol)
(Phenylthio)trimethylsilane, Phenyl trimethylsilyl sulfide, S-(Trimethylsilyl)thiophenol
Trimethylsilylthiobenzene
[EINECS(EC#)]

224-916-7
[Molecular Formula]

C9H14SSi
[MDL Number]

MFCD00008272
[Molecular Weight]

182.36
[MOL File]

4551-15-9.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to light yellow liquid
[Boiling point ]

72 °C/8 mmHg (lit.)
[density ]

0.963 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.532(lit.)
[Fp ]

87 °F
[storage temp. ]

Flammables area
[solubility ]

sol organic solvents; incompatible with strong acids and strong oxidizing agents.
[Specific Gravity]

0.963
[Water Solubility ]

Hydrolyzes in water.
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[Sensitive ]

Moisture Sensitive
[BRN ]

1905944
[CAS DataBase Reference]

4551-15-9(CAS DataBase Reference)
[EPA Substance Registry System]

Silane, trimethyl(phenylthio)- (4551-15-9)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R10:Flammable.
R20:Harmful by inhalation.
R38:Irritating to the skin.
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

3
[F ]

3-10-13-21
[TSCA ]

Yes
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29310099
Hazard InformationBack Directory
[Chemical Properties]

clear colorless to light yellow liquid
[Physical properties]

bp 93–99 °C/12 mmHg; d 0.967 g cm?3.
[Uses]

(Phenylthio)trimethylsilane can be used in selective carbonyl protection; preparation of thioesters and cleavage of ethers.
[Purification Methods]

Phenylthio trimethylsilane (trimethyl phenylthio silane) [4551-15-9] M 182.4, b 95 -9 9o/12mm, d 4 0.97. Purification is as for phenyl trimethyl silylmethyl sulfide.
Spectrum DetailBack Directory
[Spectrum Detail]

PHENYLTHIOTRIMETHYLSILANE(4551-15-9)MS
PHENYLTHIOTRIMETHYLSILANE(4551-15-9)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Phenylthiotrimethylsilane, 95%(4551-15-9)
[Alfa Aesar]

(Phenylthio)trimethylsilane, 97%(4551-15-9)
[Sigma Aldrich]

4551-15-9(sigmaaldrich)
[TCI AMERICA]

(Phenylthio)trimethylsilane,>90.0%(GC)(4551-15-9)
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