Identification | More | [Name]
5'-FLUORO-2'-HYDROXYPROPIOPHENONE | [CAS]
443-09-4 | [Synonyms]
1-(5-Fluoro-2-hydroxyphenyl) 2-hydroxy-5-fluoropropiophenone 5'-FLUORO-2'-HYDROXYPROPIOPHENONE 1-(5-FLUORO-2-HYDROXYPHENYL)PROPAN-1-ONE 1-Propanone,1-(5-fluoro-2-hydroxyphenyl)- JRH-01109, 1-(5-Fluoro-2-hydroxyphenyl)propan-1-one, 97% | [Molecular Formula]
C9H9FO2 | [MDL Number]
MFCD00218583 | [Molecular Weight]
168.16 | [MOL File]
443-09-4.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R22:Harmful if swallowed. R37/38:Irritating to respiratory system and skin . R41:Risk of serious damage to eyes. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S39:Wear eye/face protection . | [WGK Germany ]
3
| [Hazard Note ]
Irritant |
Hazard Information | Back Directory | [Preparation]
Preparation by Fries rearrangement of p-fluorophenyl propionate (b.p.18–20 118–120°) with aluminium chloride at 150° for 1 h (80–81%) or at reflux for 30 min (57%) Also obtained by demethylation of 5-fluoro-2-methoxy-propiophenone (b.p.13 132°) with refluxing pyridinium chloride for 15 min (76%). |
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