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ChemicalBook--->CAS DataBase List--->4224-69-5

4224-69-5

4224-69-5 Structure

4224-69-5 Structure
IdentificationMore
[Name]

Methyl 2-(bromomethyl)acrylate
[CAS]

4224-69-5
[Synonyms]

2-BROMOMETHYL METHYL ACRYLATE
METHYL 2-(BROMOMETHYL)ACRYLATE
2-(bromomethyl)-2-propenoicacimethylester
2-(bromomethyl)-acrylicacimethylester
methyl2-(bromomethyl)-2-propenoate
alpha-(Bromomethyl)-acrylic acid methyl ester
2-Propenoic acid, 2-(bromomethyl)-, methyl ester
2-(Bromomethyl)acrylic acid methyl ester
Methyl 2-(bromomethyl)propenoate
α-(Bromomethyl)acrylic acid methyl ester
[Molecular Formula]

C5H7BrO2
[MDL Number]

MFCD00011697
[Molecular Weight]

179.01
[MOL File]

4224-69-5.mol
Chemical PropertiesBack Directory
[Appearance]

Clear colorless to slightly brownish liquid
[Boiling point ]

35-37 °C/1.3 mmHg (lit.)
[density ]

1.489 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.490(lit.)
[Fp ]

173 °F
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Liquid
[color ]

Clear colorless to slightly brownish
[BRN ]

1852481
[Stability:]

Light Sensitive
[InChIKey]

CFTUQSLVERGMHL-UHFFFAOYSA-N
[CAS DataBase Reference]

4224-69-5(CAS DataBase Reference)
[NIST Chemistry Reference]

Methyl 2-(bromomethyl)acrylate(4224-69-5)
[EPA Substance Registry System]

2-Propenoic acid, 2-(bromomethyl)-, methyl ester (4224-69-5)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

UN 2810 6.1/PG 2
[WGK Germany ]

3
[RTECS ]

AS4900000
[F ]

8-10
[HS Code ]

29161900
Hazard InformationBack Directory
[Chemical Properties]

Clear colorless to slightly brownish liquid
[Uses]

Methyl (2-bromomethyl)acrylate (MBrMA) may be used as chain transfer agents in the emulsion polymerization of methyl methacrylate (MMA) and styrene. MBrMA can undergo nucleophilic substitution of carboxylic acid to form methyl 2-(acyloxymethyl)acrylates.
[Synthesis Reference(s)]

Organic Syntheses, Coll. Vol. 7, p. 319, 1990
Synthetic Communications, 16, p. 387, 1986 DOI: 10.1080/00397918608057713
Spectrum DetailBack Directory
[Spectrum Detail]

Methyl 2-(bromomethyl)acrylate(4224-69-5)1HNMR
Methyl 2-(bromomethyl)acrylate(4224-69-5)FT-IR
Methyl 2-(bromomethyl)acrylate(4224-69-5)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Methyl 2-(bromomethyl)acrylate, 96%(4224-69-5)
[Sigma Aldrich]

4224-69-5(sigmaaldrich)
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