Identification | More | [Name]
3-Chloro-2-butanone | [CAS]
4091-39-8 | [Synonyms]
1-ACETYL-1-CHLOROETHANE 1-CHLOROETHYL METHYL KETONE 2-CHLORO-3-BUTANONE 3-CHLORO-2-BUTANONE 3-CHLOROBUTANONE 3-CL-MEK 3-chloro-2-butanon 3-Chloro-2-oxobutane~Methyl alpha-chloroethyl ketone Chlorobutanone 3-chlorobutan-2-one 3-CHLORO-2-BUTANONE, WACKER QUALITY 3-Chloro-2-butanone, tech., 95% 2-Butanone, 3-chloro- 3-chloro-2-oxobutane chloro-mek methyl à-chloroethyl ketone 3-CHLORO-2-BUTANONE 96+% 3-Chloro-2-butanone, 95%, tech. | [EINECS(EC#)]
223-834-9 | [Molecular Formula]
C4H7ClO | [MDL Number]
MFCD00000865 | [Molecular Weight]
106.55 | [MOL File]
4091-39-8.mol |
Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R10:Flammable. R22:Harmful if swallowed. R36/37/38:Irritating to eyes, respiratory system and skin . R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [RIDADR ]
UN 1224 3/PG 3
| [WGK Germany ]
3
| [RTECS ]
EL7062000
| [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29147090 |
Hazard Information | Back Directory | [Chemical Properties]
CLEAR YELLOW TO BROWNISH LIQUID | [Uses]
3-Chloro-2-butanone was used in production of chiral alcohols from acetophenone derivatives, β-ketoesters and N-Boc-3-pyrrolidinone by recombinant E. coli cells. It was used in the synthesis of carbene precursor, 3-aryl-4,5-dimethylthiazolium chloride. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 77, p. 5274, 1955 DOI: 10.1021/ja01625a016 | [General Description]
3-Chloro-2-butanone reacts with 1,4-dianion of acetophenone N-ethoxycarbonylhydrazone to yield pyrazoline derivatives. |
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