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ChemicalBook--->CAS DataBase List--->37943-90-1

37943-90-1

37943-90-1 Structure

37943-90-1 Structure
IdentificationMore
[Name]

Diphenyl-2-pyridylphosphine
[CAS]

37943-90-1
[Synonyms]

2-(DIPHENYLPHOSPHINO)PYRIDINE
DIPHENYL-2-PYRIDYLPHOSPHINE
DPPPY/DIPHENYL-2-PYRIDYLPHOSPHINE
Diphenyl-2-pyridylphosphine ,97%
[EINECS(EC#)]

629-049-1
[Molecular Formula]

C17H14NP
[MDL Number]

MFCD00192108
[Molecular Weight]

263.27
[MOL File]

37943-90-1.mol
Chemical PropertiesBack Directory
[Appearance]

Yellow to orange crystalline powder
[Melting point ]

82-84 °C (dec.) (lit.)
[Boiling point ]

163 °C(Press: 0.05 Torr)
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

Soluble in toluene. (almost transparency)
[form ]

Crystalline Powder
[pka]

2.37±0.12(Predicted)
[color ]

White to yellow to tan
[Detection Methods]

HPLC,NMR
[InChIKey]

SVABQOITNJTVNJ-UHFFFAOYSA-N
[CAS DataBase Reference]

37943-90-1(CAS DataBase Reference)
[Storage Precautions]

Store under nitrogen
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[HS Code ]

29333990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Sodium hydroxide-->Hydrochloric acid-->Ethyl acetate-->Tetrahydrofuran-->Dichloromethane-->Sodium-->PETROLEUM ETHER-->Magnesium sulfate-->Acetone-->n-Butyllithium-->Ammonium chloride-->Triphenylphosphine-->Lithium-->2-Chloropyridine-->Diphenylphosphine-->Pyridine, 2-(diphenylphosphinyl)--->Diphenyl(trimethylsilyl)phosphine
Hazard InformationBack Directory
[Chemical Properties]

Yellow to orange crystalline powder
[Uses]

Diphenyl-2-pyridylphosphine is an organophosphorous compound that is a widely used mono-pyridylphosphine ligand in transition metal complexes for catalysis.
[Uses]

suzuki reaction
[reaction suitability]

reagent type: ligand
reaction type: Carbonatations
reagent type: ligand
reaction type: Dehydrogenation
reagent type: ligand
reaction type: Hydration Reaction
reagent type: ligand
reaction type: Mitsunobu Reaction
reagent type: ligand
reaction type: Stannylation
Questions And AnswerBack Directory
[Reaction]

Ligand for the palladium-catalyzed distannylation of ortho-quinodimethanes
Ligand for the palladium-catalyzed disilylation of o-quinodimethanes to synthesize 9- and 10-membered disilacarbocycles
Ligand for the palladium-catalyzed alkoxycarbonylation of allenes Reactions of 37943-90-1
Spectrum DetailBack Directory
[Spectrum Detail]

Diphenyl-2-pyridylphosphine(37943-90-1)FT-IR
Diphenyl-2-pyridylphosphine(37943-90-1)Raman
Diphenyl-2-pyridylphosphine(37943-90-1)IR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

37943-90-1(sigmaaldrich)
[TCI AMERICA]

Diphenyl-2-pyridylphosphine,>97.0%(GC)(37943-90-1)
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