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ChemicalBook--->CAS DataBase List--->3558-24-5

3558-24-5

3558-24-5 Structure

3558-24-5 Structure
IdentificationMore
[Name]

1-Methyl-2-phenylindole
[CAS]

3558-24-5
[Synonyms]

1-METHYL-2-PHENYL-1H-INDOLE
1-METHYL-2-PHENYLINDOLE
N-METHYL-2-PHENYLINDOLE
1-methyl-2-phenyl-1h-indol
1-Methyl-2-Phenylindol
1-METHYL-2-PHENYLINDOLE 99+%
1H-Indole, 1-methyl-2-phenyl-
2-Phenyl-N-methylindole
2-Phenyl-1-methyl-1H-indole
[EINECS(EC#)]

222-618-1
[Molecular Formula]

C15H13N
[MDL Number]

MFCD00022892
[Molecular Weight]

207.27
[MOL File]

3558-24-5.mol
Chemical PropertiesBack Directory
[Appearance]

WHITE TO LIGHT GREEN-TAN CRYSTALS OR CRYST. POWDER
[Melting point ]

98-100 °C (lit.)
[Boiling point ]

336.3°C (rough estimate)
[density ]

1.0880 (rough estimate)
[refractive index ]

1.5720 (estimate)
[storage temp. ]

2-8°C
[form ]

powder to crystal
[color ]

White to Light yellow
[Detection Methods]

HPLC
[BRN ]

148770
[InChI]

InChI=1S/C15H13N/c1-16-14-10-6-5-9-13(14)11-15(16)12-7-3-2-4-8-12/h2-11H,1H3
[InChIKey]

SFWZZSXCWQTORH-UHFFFAOYSA-N
[SMILES]

N1(C)C2=C(C=CC=C2)C=C1C1=CC=CC=C1
[CAS DataBase Reference]

3558-24-5(CAS DataBase Reference)
[EPA Substance Registry System]

3558-24-5(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[TSCA ]

Yes
[HS Code ]

29339900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Sodium hydroxide-->Acetic acid-->Dimethyl sulfate-->Polyphosphoric acid-->Acetophenone-->Phenylhydrazine
[Preparation Products]

BASIC RED 29-->BASIC RED 29-->sodium hydrogen -2-ethoxy-5-[[4-[[4-[(4-ethoxy-3-sulphonatophenyl)amino]phenyl]-(1H-indol-3-yl-1-methyl-2-phenyl)methylene]-2,5-cyclohexadien-1-ylidene]amino]benzenesulphonate-->sodium hydrogen -2-hydroxy-5-[[4-[[4-[(4-hydroxy-3-sulphonatophenyl)amino]phenyl](1-methyl-2-phenyl-1H-indol-3-yl)methylene]-2,5-cyclohexadien-1-ylidene]amino]benzenesulphonate-->3-(dicyclohexylphosphino)-1-methyl-2-phenyl-1H-indole
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1-Methyl-2-phenylindole(3558-24-5).msds
Hazard InformationBack Directory
[Chemical Properties]

WHITE TO LIGHT GREEN-TAN CRYSTALS OR CRYST. POWDER
[Uses]

Reactant for preparation of:
  • Cyano indoles
  • Difluorohydroxy indoles

Reactant for:
  • Carboxylation of indoles
  • Allylation of indoles
  • Formylation of indoles
  • Nitrosylation of indoles
[Synthesis Reference(s)]

Tetrahedron Letters, 34, p. 2059, 1993 DOI: 10.1016/S0040-4039(00)60345-3
[General Description]

Reaction of 1-methyl-2-phenylindole with nitrogen dioxide or with nitrous acid (NaNO2-CH3COOH) in benzene has been studied. 1-Methyl-2-phenylindole is reported to react with malondialdehyde (MDA) and 4-hydroxyalkenals to afford a stable chromophore with intense maximal absorbance at 586nm.
Spectrum DetailBack Directory
[Spectrum Detail]

1-Methyl-2-phenylindole(3558-24-5)MS
1-Methyl-2-phenylindole(3558-24-5)13CNMR
1-Methyl-2-phenylindole(3558-24-5)IR1
1-Methyl-2-phenylindole(3558-24-5)IR2
1-Methyl-2-phenylindole(3558-24-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1-Methyl-2-phenylindole, 99%(3558-24-5)
[Alfa Aesar]

1-Methyl-2-phenylindole, 99%(3558-24-5)
[Sigma Aldrich]

3558-24-5(sigmaaldrich)
[TCI AMERICA]

1-Methyl-2-phenylindole,>99.0%(T)(3558-24-5)
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