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ChemicalBook--->CAS DataBase List--->3425-46-5

3425-46-5

3425-46-5 Structure

3425-46-5 Structure
IdentificationMore
[Name]

POTASSIUM SELENOCYANATE
[CAS]

3425-46-5
[Synonyms]

POTASSIUM SELENOCYANATE
CHNSe·K
potassiumselenoisocyanate
Selenocyanicacid,potassiumsalt
POTASSIUM SELENOCYANATE, REAGENTPLUS, >=99%
Potassiumselenocyanate,98.5%
Selenocyanic acid potassium
[EINECS(EC#)]

222-320-1
[Molecular Formula]

CKNSe
[MDL Number]

MFCD00011366
[Molecular Weight]

144.08
[MOL File]

3425-46-5.mol
Chemical PropertiesBack Directory
[Appearance]

white to light beige crystalline powder or needles
[Melting point ]

147 °C
[density ]

2.347
[storage temp. ]

Poison room
[form ]

Crystalline Solid, Powder, Crystals and/or Chunks
[color ]

White to off-white
[Specific Gravity]

2.347
[Water Solubility ]

Soluble in water, ethanol, dimethyl formamide, hexamethylphosphoramide, acetonitrile and methanol. Slightly soluble in terahydrofuran.
[Sensitive ]

Moisture Sensitive
[BRN ]

3912121
[Exposure limits]

ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3
[InChI]

InChI=1S/CHNSe.K/c2-1-3;/h3H;/q;+1/p-1
[InChIKey]

KYEKHFSRAXRJBR-UHFFFAOYSA-M
[SMILES]

C(#N)[Se][K]
[CAS DataBase Reference]

3425-46-5(CAS DataBase Reference)
[EPA Substance Registry System]

Selenocyanic acid, potassium salt (3425-46-5)
Safety DataBack Directory
[Hazard Codes ]

T,N
[Risk Statements ]

R23/25:Toxic by inhalation and if swallowed .
R33:Danger of cumulative effects.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S20/21:When using, do not eat, drink or smoke .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 3283 6.1/PG 2
[WGK Germany ]

3
[RTECS ]

VT1400000
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

II
[HS Code ]

28429090
[Safety Profile]

Poison by intraperitoneal route. When heated to decomposition it emits very toxic fumes of NOx, CN-, K2O, and Se. See also SELENIUM COMPOUNDS and CYANATES.
[Toxicity]

guinea pig,LD50,skin,50mg/kg (50mg/kg),SKIN AND APPENDAGES (SKIN): "DERMATITIS, OTHER: AFTER SYSTEMIC EXPOSURE",National Technical Information Service. Vol. OTS0536978,
Hazard InformationBack Directory
[Description]

Potassium selenocyanate, a crystalline solid, is a reagent for the conversion of alkyl halides to nitriles and for the production of pharmaceutical intermediates. It is also used in the field of energy storage devices.
[Chemical Properties]

white to light beige crystalline powder or needles
[Uses]

Potassium selenocyanate is used to prepare triphenylphosphine selenide by reacting with triphenylphosphine. It finds application in solid state NMR of heavy-metal nuclei which results in the preparation of several mercury thiocyanate and selenocyanate compounds.
[Application]

Potassium selenocyanate can be used to:
(1) Redox-active electrolyte to enhance the performance of carbon-based supercapacitors.
(2) Starting material for the one-pot stereoselective synthesis of alkyl styryl selenides.
(3) Precursor to synthesize Cu and Ni complexes with antioxidant/anti-inflammatory activities.
(4) Selenylating agent to prepare stereoselective selenoglycosides and selenium-linked disaccharides.
[storage]

Crystalline KSeCN is hygroscopic and decomposes with the elimination of selenium upon prolonged exposure to air. It should be stored in sealed containers. Potassium selenocyanate is a malodorous and highly toxic compound. All reactions and handling should be carried out in a well-ventilated hood.
[Purification Methods]

Dissolve it in acetone, filter and precipitate it by adding Et2O.
Spectrum DetailBack Directory
[Spectrum Detail]

POTASSIUM SELENOCYANATE(3425-46-5)IR
POTASSIUM SELENOCYANATE(3425-46-5)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Potassium selenocyanate, 99%(3425-46-5)
[Alfa Aesar]

Potassium selenocyanate, 98.5%(3425-46-5)
[Sigma Aldrich]

3425-46-5(sigmaaldrich)
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