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ChemicalBook--->CAS DataBase List--->3388-04-3

3388-04-3

3388-04-3 Structure

3388-04-3 Structure
IdentificationMore
[Name]

Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane
[CAS]

3388-04-3
[Synonyms]

1-[2-(TRIMETHOXYSILYL)ETHYL]CYCLOHEXANE-3,4-EPOXIDE
2-(3,4-EPOXYCYCLOHEXYL)ETHYLTRIMETHOXYSILANE
2-(7-OXABICYCLO[4.1.0]HEPT-3-YL)ETHYL-TRIMETHOXYSILANE
3-(2-TRIMETHOXYSILYLETHY)CYCLOHENE OXIDE
B-(3,4-EPOXYCYCLOHEXYL)ETHYLTRIMETHOXYSILANE
BETA-(3,4-EPOXYCYCLOHEXYL)-ETHYLTRIMETHOXYSILANE
TRIMETHOXY[2-(7-OXABICYCLO[4.1.0]HEPT-3-YL)ETHYL]SILANE
TRIMETHOXY(2-(OXABICYCLO(4.1.0)HEPT-3-YL)) ETHYLSILANE
((Epoxycyclohexyl)ethyl)trimethoxy silane
(3,4-epoxycyclohexyl)ethyltrimethoxysilane
2-(3,4-Epoxycyclohexyl) ethyltriacetoxysilane
3,4-Epoxycyclohexylethyltrimethoxysilane
3-[2-(Trimethoxysilyl)Ethyl]-7-oxabicyclo[4.1.0]heptane
4-[2-(Trimethoxysilyl)ethyl]-7-oxabicyclo[4.1.0]heptane
A 186
A 186 (Heterocycle)
a186(couplingagent)
beta-(3,4-epoxycyclohexyl)ethyltrimethoxy-silan
CE6250
e6250
[EINECS(EC#)]

222-217-1
[Molecular Formula]

C11H22O4Si
[MDL Number]

MFCD00014485
[Molecular Weight]

246.38
[MOL File]

3388-04-3.mol
Chemical PropertiesBack Directory
[Melting point ]

<0°C
[Boiling point ]

310 °C(lit.)
[density ]

1.065 g/mL at 25 °C(lit.)
[vapor pressure ]

0.46Pa at 25℃
[refractive index ]

n20/D 1.451(lit.)
[Fp ]

>230 °F
[storage temp. ]

Inert atmosphere,2-8°C
[form ]

liquid
[color ]

Colorless to Almost colorless
[Specific Gravity]

1.065
[Water Solubility ]

1.4g/L at 20℃
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[BRN ]

8980119
[InChIKey]

DQZNLOXENNXVAD-UHFFFAOYSA-N
[LogP]

2.5 at 20℃
[CAS DataBase Reference]

3388-04-3(CAS DataBase Reference)
[NIST Chemistry Reference]

1-[2-(Trimethoxysilyl)ethyl]cyclohexane-3,4-epoxide(3388-04-3)
[EPA Substance Registry System]

3388-04-3(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T
[Risk Statements ]

R45:May cause cancer.
[Safety Statements ]

S53:Avoid exposure-obtain special instruction before use .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[WGK Germany ]

3
[RTECS ]

VV4000000
[F ]

3-10
[TSCA ]

Yes
[HS Code ]

29319090
[Toxicity]

LD50 oral in rat: 8mL/kg
Hazard InformationBack Directory
[Uses]

Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane was used as an adhesion promoter during the fabrication of:
  • a photoacid generator activated by two photon excitation.
  • nanoscale polymeric structures (width: 65 nm) using 520 nm femtosecond pulse excitation.

Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane may be used as a precursor to form SiCOH film via sol-gel. The silane may be used to functionalize alumina nanoparticles towards the fabrication of polyamide 12/alumina nanocomposites. 4 Basalt fibers were functionalized with this silane and its consequent effect on the fabrication of basalt fiber–epoxidized vegetable oil matrix composite materials was analyzed.
[Uses]

Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane may be used as a precursor to form SiCOH film via sol-gel. The silane may be used to functionalize alumina nanoparticles towards the fabrication of polyamide 12/alumina nanocomposites. 4 Basalt fibers were functionalized with this silane and its consequent effect on the fabrication of basalt fiber–epoxidized vegetable oil matrix composite materials was analyzed.Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane can be used as a silane based coupling agent to functionalize a variety of substrates. It modifies the surface to improve the dispersion of nanoparticles. It can be used as an adhesion promoter by treating the precursor material with epoxy silanes.
[Application]

Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane was used as an adhesion promoter during the fabrication of:a photoacid generator activated by two photon excitation.nanoscale polymeric structures (width: 65 nm) using 520 nm femtosecond pulse excitation.
[Flammability and Explosibility]

Nonflammable
[Synthesis]

Synthesis_3388-04-3
The apparatus of Example B was charged with 148.8 g (1.2 mol) of 1-vinyl-3,4-epoxycyclohexane, 1.3 g of a carboxylic acid promoter, and 0.15 ml of 10% chloroplatinic acid catalyst solution. The flask contents were heated to 89?? C. and dropwise addition of 122.8 g {[1.0 mol) of trimethoxysilane was begun. The reaction temperature was controlled at 90??-95?? C. with an ice bath. Reaction was maintained at that temperature for half an hour after completion of addition, which took 18 minutes. Analysis by gas chromatography showed a yield of 90% of 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane. This example demonstrates a standard preparation of 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane using commercial chloroplatinic acid.
Spectrum DetailBack Directory
[Spectrum Detail]

Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane(3388-04-3)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

3388-04-3(sigmaaldrich)
[TCI AMERICA]

2-(3,4-Epoxycyclohexyl)ethyltrimethoxysilane,>97.0%(GC)(3388-04-3)
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