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ChemicalBook--->CAS DataBase List--->3225-26-1

3225-26-1

3225-26-1 Structure

3225-26-1 Structure
IdentificationMore
[Name]

4-BENZOYLOXY-TEMPO
[CAS]

3225-26-1
[Synonyms]

4-BENZOYLOXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL
4-BENZOYLOXY-TEMPO
4-BENZOYLOXY-TEMPO FREE RADICAL
4-HYDROXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL BENZOATE
4-HYDROXY-TEMPO BENZOATE
4-HYDROXY-TEMPO BENZOATE, FREE RADICAL
4-Benzoyloxy-2,2,6,6-tetramethylpiperidinyloxy, free radical~4-Hydroxy-TEMPO benzoate, free radical
4-Benzyloxy-TEMPO,freeradical
4-HYDROXY-TEMPO-BENZOATE,97%
4-HYDROXY-2,2,6,6-TETRAMETHYLPIPERIDINE 1-OXYL BENZOATE (FREE RADICAL)
2,2,6,6-Tetramethyl-4-piperidinyl benzoate
4-HYDROXY-TEMPO BENZOATE FREE RADICAL 97%
4-BENZOYLOXY-TEMPO FREE RADICAL 97%
4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Benzoate Free Radical [Catalyst for Oxidation]
4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-oxyl benzoate, 4-Hydroxy-TEMPO benzoate
[EINECS(EC#)]

807-702-3
[Molecular Formula]

C16H22NO3 *
[MDL Number]

MFCD00075563
[Molecular Weight]

276.35
[MOL File]

3225-26-1.mol
Chemical PropertiesBack Directory
[Appearance]

orange crystalline powder
[Melting point ]

99-101 °C (lit.)
[density ]

0.001g/cm3 at 20℃
[vapor pressure ]

11.5Pa at 20℃
[form ]

Crystalline
[color ]

Light yellow to Brown
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[BRN ]

1431263
[LogP]

3.13 at 20℃ and pH7.88
[CAS DataBase Reference]

3225-26-1(CAS DataBase Reference)
Safety DataBack Directory
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[HS Code ]

29329990
Hazard InformationBack Directory
[Chemical Properties]

orange crystalline powder
[Uses]

Recycling catalyst in hypochlorite/bromite-nitroxide oxidizing system for conversion of alcohols to aldehydes, ketones, and carboxylic acids. It circumvents the need to use a catalytic or stoichiometric heavy metal oxidant.
[Uses]

4-Hydroxy-TEMPO Benzoate, Free Radical is a recycling catalyst in a hypochlorite/bromite-nitroxide oxidizing system for conversion of alcohols to aldehydes, ketones, and carboxylic acids. It circumvents the need to use a catalytic or stoichiometric heavy metal oxidant.
[Definition]

ChEBI: 4-hydroxy-TEMPO benzoate is a member of the class of piperidines that is TEMPO carrying a benzoyloxy group at position 4. It has a role as a radical scavenger and a spin probe. It is a member of aminoxyls, a member of piperidines and a benzoate ester. It is functionally related to a 4-hydroxy-TEMPO.
[General Description]

4-Hydroxy-TEMPO benzoate is a 4-substituted 2,2,6,6-tetramethylpiperidyl-1-oxy (TEMPO) derivative.
Spectrum DetailBack Directory
[Spectrum Detail]

4-BENZOYLOXY-TEMPO(3225-26-1)IR
4-BENZOYLOXY-TEMPO(3225-26-1)Raman
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

3225-26-1(sigmaaldrich)
[TCI AMERICA]

4-Hydroxy-2,2,6,6-tetramethylpiperidine 1-Oxyl Benzoate  Free Radical [Catalyst for Oxidation],>97.0%(GC)(3225-26-1)
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