| Identification | More | [Name]
1,1-Di(tert-butylperoxy)cyclohexane | [CAS]
3006-86-8 | [Synonyms]
1,1-BIS(TERT-BUTYLPEROXY)CYCLOHEXANE
1,1-DI(TERT-BUTYLPEROXY)CYCLOHEXANE
cyclohexylidenebis(tert-butyl)peroxide
Luperox 331M80
LUPEROX(TM) 331M80
Trigonox 22
TRIGONOX(R) 22
Peroxide,cyclohexylidenebis[(1,1-dimethylethyl)
1,1-bis(T-butylperoxy)cyclohexane
1,1-Bis(tert-butylperoxy)cyclohexane solution
DP275B
1,1-BIS(T-BUPEROXY)CYCLOHEXANE, 80 WT. %
1 1-BIS(T-BUTYLPEROXY)CYCLOHEXANE TECH&
50%solutioninmineraloil
1,1-Di(tert-butylperoxy)cyclohexane, 50% solution in mineral oil
1,1-Di-(tert.-butylperoxy)-cyclohexan
Cyclohexylidenebis[(1,1-dimethylethyl)peroxide]
Dibutyl peroxycyclohexanone paste
Initiating agent DP275B
1,1-Bis(tert-butylperoxy)cyclohexane (Luperox(R) 331M80) solution | [EINECS(EC#)]
221-111-2 | [Molecular Formula]
C14H28O4 | [MDL Number]
MFCD00084800 | [Molecular Weight]
260.37 | [MOL File]
3006-86-8.mol |
| Chemical Properties | Back Directory | [Appearance]
clear liquid | [Melting point ]
65 °C (SADT) | [Boiling point ]
52-54 °C (0.1 mmHg) | [density ]
0.891 g/mL at 25 °C
| [vapor pressure ]
4.88hPa at 25℃ | [refractive index ]
n20/D 1.435
| [Fp ]
155 °F
| [storage temp. ]
Refrigerator (+4°C) | [form ]
Liquid | [color ]
Clear | [Water Solubility ]
miscible | [InChI]
InChI=1S/C14H28O4/c1-12(2,3)15-17-14(10-8-7-9-11-14)18-16-13(4,5)6/h7-11H2,1-6H3 | [InChIKey]
HSLFISVKRDQEBY-UHFFFAOYSA-N | [SMILES]
C1(CCCCC1)(OOC(C)(C)C)OOC(C)(C)C | [LogP]
7.2 at 25℃ | [CAS DataBase Reference]
3006-86-8(CAS DataBase Reference) | [EPA Substance Registry System]
3006-86-8(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
O,N,T | [Risk Statements ]
R7:May cause fire.
R62:Possible risk of impaired fertility.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R36/37/38:Irritating to eyes, respiratory system and skin .
R61:May cause harm to the unborn child. | [Safety Statements ]
S17:Keep away from combustible material .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S3/7:Keep container tightly closed in a cool place .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S60:This material and/or its container must be disposed of as hazardous waste .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S14:Keep away from ... (incompatible materials to be indicated by the manufacturer) .
S53:Avoid exposure-obtain special instruction before use . | [RIDADR ]
UN 3103 5.2
| [WGK Germany ]
2
| [HazardClass ]
5.2 | [PackingGroup ]
II | [HS Code ]
29096000 |
| Hazard Information | Back Directory | [Reactivity Profile]
The explosive instability of the lower dialkyl peroxides (e.g., dimethyl peroxide) and 1,1-bis-peroxides decreases rapidly with increasing chain length and degree of branching, the di-tert-alkyl derivatives being amongst the most stable class of peroxides. Though many 1,1-bis-peroxides have been reported, few have been purified because of the higher explosion hazards compared with the monofunctional peroxides. 1,1-DI-(TERT-BUTYLPEROXY)CYCLOHEXANE, [<= 50% WITH PHLEGMATIZER] is unlikely that this derivative would be particularly unstable compared to other peroxides in it's class, Bretherick 2nd ed., p 44 1979. | [Chemical Properties]
clear liquid | [Uses]
Polymerization initiator. | [Definition]
1,1-Di (tert-butylperoxy) cyclohexane (DTBPH) is a commercial liquid organic peroxide that is to be in aliphatic hydrocarbon solvent and transported and stored under limited temperature[1]. | [Flammability and Explosibility]
Notclassified | [Toxics Screening Level]
The initial threshold screening level (ITSL) for 1,1-Di-(tert-butylperoxy)cyclohexane is set at trace, 0.1 μg/m3 based on an annual averaging time. | [References]
[1] Jo-Ming Tseng . “The thermal hazard evaluation of 1,1-di (tert-butylperoxy) cyclohexane by DSC using non-isothermal and isothermal-kinetic simulations.” Journal of Loss Prevention in The Process Industries 25 4 (2012): Pages 703-708. |
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