| Identification | More | [Name]
Allyl chloroformate | [CAS]
2937-50-0 | [Synonyms]
ACF
ALLYL CHLOROCARBONATE
ALLYL CHLOROFORMATE
CHLOROFORMIC ACID ALLYL ESTER
2-propenylchloroformate
ALLYLCHLOROFORMATE(ACF)
allylesterkyselinychlormravenci
carbonochloridicacid,2-propenylester
chlorocarbonicacidallylester
chloro-formicaciallylester
Ally chloroformate
ALLYL CHLOROFORMATE, STAB.
allyl chlorofomate
Prop-1-enylchlorocarbonate
Allyl carbonochloridate
(Allyloxycarbonyl) chloride
Chloridocarbonic acid allyl
Chloridocarbonic acid allyl ester | [EINECS(EC#)]
220-916-6 | [Molecular Formula]
C4H5ClO2 | [MDL Number]
MFCD00000648 | [Molecular Weight]
120.53 | [MOL File]
2937-50-0.mol |
| Chemical Properties | Back Directory | [Appearance]
Colorless liquid | [Melting point ]
106℃ | [Boiling point ]
109 °C | [density ]
1.134 g/mL at 20 °C(lit.)
| [vapor pressure ]
3.67 psi ( 20 °C)
| [refractive index ]
n20/D 1.422(lit.)
| [Fp ]
88 °F
| [storage temp. ]
2-8°C
| [solubility ]
Chloroform | [form ]
Liquid | [color ]
Clear slightly yellow to light orange to reddish brown | [Odor]
Extremely irritating, causes tears; pungent. | [BRN ]
773915 | [Stability:]
Moisture Sensitive | [CAS DataBase Reference]
2937-50-0(CAS DataBase Reference) | [NIST Chemistry Reference]
Allyl chloroformate(2937-50-0) | [EPA Substance Registry System]
2937-50-0(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T+ | [Risk Statements ]
R10:Flammable.
R22:Harmful if swallowed.
R26:Very Toxic by inhalation.
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 1722 6.1/PG 1
| [WGK Germany ]
3
| [RTECS ]
LQ5775000
| [F ]
19 | [HazardClass ]
6.1(b) | [PackingGroup ]
I | [HS Code ]
29159000 | [Safety Profile]
Poison by inhalation and ingestion. Corrosive. Dangerous when exposed to heat, open flame (or sparks), or powerful oxidizers. Can react with oxidizing materials. To fight fire, use alcohol foam, spray or mist, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also ALLYL COMPOUNDS and ESTERS. | [Hazardous Substances Data]
2937-50-0(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
A colorless liquid with a pungent odor. Flash point 88°F. Corrosive to metals and tissue. Very toxic by inhalation, ingestion and/or skin contact. Vapors are heavier than air. | [Reactivity Profile]
Acid halides, such as ALLYL CHLOROCARBONATE(2937-50-0), are water reactive; some are violently reactive. They are incompatible with strong oxidizing agents, alcohols, amines, alkali. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. | [Air & Water Reactions]
Highly flammable. Water reaction produces heat and acidic HCl. In the presence of moist air, corrosive hydrogen chloride is produced. | [Health Hazard]
Vapor irritates eyes and respiratory tract. Contact with liquid causes eye and skin irritation, and ingestion irritates mouth and stomach. | [Chemical Properties]
Colorless liquid | [Uses]
Allyl Chloroformate is used in the synthesis of poly(ethylene oxide) hybrid systems for therapeutic applications and drug delivery. Also used in the synthesis of benzothiazole derivatives with potent anti-tumor properties. | [Chemical Reactivity]
Reactivity with Water Reacts slowly generating hydrogen chloride; Reactivity with Common Materials: Corrosive metals; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Flush with water, rinse with sodium bicarbonate solution; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent. |
|
|