| Identification | Back Directory | [Name]
Sodium trifluoromethanesulfinate | [CAS]
2926-29-6 | [Synonyms]
finate
Langlois reagent
SodiuM Triflinate
Sodium triflinate >=95.0% (T)
sodium trifluoromethanesulfina
Sodium trifluoromethylsulfinate
Sodium trifluoromethyl sulfonate
SODIUM TRIFLUOROMETHANESULFINATE
SODIUM TRIFLUOROMETHANESULPHINATE
Sodium trifluoromethylene sulfonate
Sodium trifluoromethanesulphinate 96%
sodium trifluoromethanesulfinate CF3NaO2S
TRIFLUOROMETHANESULFINIC ACID SODIUM SALT
Trifluoromethanesulphinic acid, sodium salt
Sodium trifluoromethanesulfinate, tech grade
Methanesulfinic acid,1,1,1-trifluoro-, sodiuM salt
Sodium trifluoromethanesulfinate, 97%, for synthesis
Methanesulfinic acid,1,1,1-trifluoro-, sodium salt (1:1) | [EINECS(EC#)]
423-490-1 | [Molecular Formula]
CF3NaO2S | [MDL Number]
MFCD03092989 | [MOL File]
2926-29-6.mol | [Molecular Weight]
156.06 |
| Chemical Properties | Back Directory | [Melting point ]
<325°C | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
Water (Sparingly) | [form ]
powder | [color ]
white | [BRN ]
3723394 | [InChIKey]
KAVUKAXLXGRUCD-UHFFFAOYSA-M |
| Hazard Information | Back Directory | [Chemical Properties]
White to light yellow solid | [Uses]
Efficient sulfinate salt for the trifluoromethylation of various aryls, aryl boronic acids, alkenes, and alkynes. | [Solubility in water]
soluble in H2O, slightly soluble in MeOH, MeCN, and acetone.
| [Synthesis]
At first, an aqueous solution was prepared by dissolving 37.5 g of sodium sulfite in 150 g of water. Then, a metal pressure-proof reactor was charged with this aqueous solution. After that, the atmosphere of the reactor was removed to obtain a reduced pressure. 10.7 g of trifluoromethanesulfonic fluoride was added to the reactor, stirring at 5° C. for 4 hr. The resulting reaction liquid was neutralized with sodium carbonate, followed by water removal. Then, methanol was added to the remaining solid matter to extract the target product. The resulting methanol solution was concentrated to dryness, thereby obtaining 9.7 g of sodium trifluoromethanesulfinate (yield: 88%).
 |
|
|