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ChemicalBook--->CAS DataBase List--->27905-45-9

27905-45-9

27905-45-9 Structure

27905-45-9 Structure
IdentificationMore
[Name]

1H,1H,2H,2H-Heptadecafluorodecyl acrylate
[CAS]

27905-45-9
[Synonyms]

1H,1H,2H,2H-HEPTADECAFLUORODECYL ACRYLATE
1H,1H,2H,2H-HEPTADECAFLUORO-N-DECYL ACRYLATE
1H,1H,2H,2H-PERFLUORODECYL ACRYLATE
2-(PERFLUOROOCTYL)ETHYL ACRYLATE
3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL ACRYLATE
ACRYLIC ACID 1H,1H,2H,2H-HEPTADECAFLUORO-N-DECYL ESTER
ACRYLIC ACID 1H,1H,2H,2H-PERFLUORODECYL ESTER
DAIKIN R-1820
TETRAHYDROPERFLUORODECYL ACRYLATE
1,1,2,2-Tetrahydroperfluorodecylacrylate
2-propenoicacid,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylest
2-Propenoicacid,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylester
Acrylic acid 1H,1H,2H,2H-perfluorodecyl ester~1H,1H,2H,2H-Heptadecafluorodecyl acrylate
Perfluorodecylacrylate
1H,1H,2H,2H-Heptadecafluorodecyl acrylate, stabilized, 97%
acrylic acid 1h,1h,2h,2h-heptadecafluorodecyl ester
1H,1H,2H,2H-Perfluorodecyl acrylate 95%
1H,1H,2H,2H-Perfluorodecylacrylate95%
Perfluoroalkylethylacrylate
perfluorooctylethyl acrylate
[EINECS(EC#)]

248-722-7
[Molecular Formula]

C13H7F17O2
[MDL Number]

MFCD00042306
[Molecular Weight]

518.17
[MOL File]

27905-45-9.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless liquid
[Melting point ]

-3°C
[Boiling point ]

90 °C4 mm Hg(lit.)
[density ]

1.637 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.337(lit.)
[Fp ]

>230 °F
[storage temp. ]

0-6°C
[solubility ]

Chloroform, Methanol (Slightly), Water (Sparingly)
[form ]

Liquid
[color ]

Clear colorless
[Specific Gravity]

1.596
[BRN ]

5173337
[Stability:]

Light Sensitive
[InChIKey]

QUKRIOLKOHUUBM-UHFFFAOYSA-N
[CAS DataBase Reference]

27905-45-9(CAS DataBase Reference)
[EPA Substance Registry System]

1,1,2,2-Tetrahydroperfluorodecyl acrylate (27905-45-9)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[F ]

10-23
[Hazard Note ]

Irritant
[TSCA ]

T
[HazardClass ]

IRRITANT
[HS Code ]

29161290
Hazard InformationBack Directory
[Chemical Properties]

clear colorless liquid
[Uses]

(Perfluorooctyl)ethyl Acrylate is a reagent used in the synthesis of parahydrophobic polymer coatings, as well as polymer brushes for controlling surface lubrication.
[Application]

1H,1H,2H,2H-Heptadecafluorodecyl acrylate can be applied as follows:
(1) Coatings Industry: Due to their low surface tension and excellent heat resistance, 1H,1H,2H,2H-Heptadecafluorodecyl acrylate are commonly used in the preparation of high-performance surface coatings, such as water-repellent, oil-repellent, corrosion-repellent, anti-adhesive and temperature-resistant coatings[1-2].
(2) Lubricants: It can be used as a lubricant, especially where oil and water resistance is required.
(3) Surface Modifiers: In surface modification of textiles, plastics and other materials, it can provide special surface properties such as anti-staining and anti-adhesion[3].
(4) Electronic encapsulation material: Due to its chemical inertness and heat resistance, it can also be used as encapsulation material for electronic products, such as liquid crystal displays and fibre optic manufacturing.
[Definition]

1H,1H,2H,2H-Heptadecafluorodecyl acrylate is a semi-volatile fluorinated organic compound and is in polluted air in Asia and the western United States during the spring. The structure of this substance contains multiple fluorine atoms and a terminal olefin unit. It has high chemical reactivity and is sensitive to intense light. Perfluorooctylethyl acrylate contains an unsaturated double-bond unit and can be used to prepare perfluoroacrylate polymers.
[Research]

Latex based upon fluorinated acrylates such as perfluorooctylethyl methacrylate (FMA) and perfluorooctylethyl acrylate (FA; 1H,1H,2H,2H-Heptadecafluorodecyl acrylate) and fluorine-free acrylates such as n-butyl methacrylate (BMA) was prepared using emulsion polymerization in the presence of octadecyltrimethylammonium bromide (C18TAB) and 2,2′-azobis(2-amidinopropane) dihydrochloride (V50) as water-soluble azo initiator[4].
[References]

[1] VIRENDRA KUMAR. Fluorocarbon Coatings Via Plasma Enhanced Chemical Vapor Deposition of 1H,1H,2H,2H‐perfluorodecyl Acrylate ‐ 2, Morphology, Wettability and Antifouling Characterization[J]. Plasma Processes and Polymers, 2010. DOI:10.1002/PPAP.201000038.
[2] N. YOSHINO. Syntheses and Reactions of Metal Organics. XVII. Synthesis of Silane Coupling Agent Having Fluorocarbon Chain and Surface Modification of Glass Plate[J]. Bulletin of the Chemical Society of Japan, 1993. DOI:10.1246/BCSJ.66.472.
[3] JIYOUNG LEE . Robust and superomniphobic core-shell SiO2@poly(1H,1H,2H,2H-heptadecafluorodecyl methacrylate-co-methyl methacrylate) coating materials synthesized by thiol lactam initiated radical polymerization[J]. Progress in Organic Coatings, 2020. DOI:10.1016/j.porgcoat.2020.105851.
[4] Reinhard F. Linemann. “Latex Blends of Fluorinated and Fluorine-Free Acrylates: Emulsion Polymerization and Tapping Mode Atomic Force Microscopy of Film Formation.” Macromolecules 32 6 (1999): 1715–1721.
Spectrum DetailBack Directory
[Spectrum Detail]

1H,1H,2H,2H-Heptadecafluorodecyl acrylate(27905-45-9)MS
1H,1H,2H,2H-Heptadecafluorodecyl acrylate(27905-45-9)1HNMR
1H,1H,2H,2H-Heptadecafluorodecyl acrylate(27905-45-9)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1H,1H,2H,2H-Heptadecafluorodecyl acrylate, stabilized, 97%(27905-45-9)
[Alfa Aesar]

1H,1H,2H,2H-Perfluorodecyl acrylate, 96%, stab. with 100ppm 4-methoxyphenol(27905-45-9)
[Sigma Aldrich]

27905-45-9(sigmaaldrich)
[TCI AMERICA]

1H,1H,2H,2H-Heptadecafluorodecyl Acrylate  (stabilized with MEHQ),>97.0%(GC)(27905-45-9)
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