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ChemicalBook--->CAS DataBase List--->27757-85-3

27757-85-3

27757-85-3 Structure

27757-85-3 Structure
IdentificationMore
[Name]

2-Thiophenemethylamine
[CAS]

27757-85-3
[Synonyms]

1-THIEN-2-YLMETHANAMINE
2-(2-AMINOMETHYL)THIOPHENE
2-(AMINOMETHYL)THIOPHENE
2-THENYLAMINE
2-THIENYLMETHYLAMINE
2-THIOPHENEMETHYLAMINE
AKOS BBS-00003607
C-THIOPHEN-2-YL-METHYLAMINE
LABOTEST-BB LT00053452
RARECHEM AL BW 0257
THIOPHENE-2-METHYLAMINE
TIMTEC-BB SBB004315
2-Thienylmethanamine
2-THIOPHENEMETHANAMINE
2-ThiophenMethylamine
Thiophene-2-methylamine,98+%
(THIOPHEN-2-YL)METHYLAMINE
2-Thiophenemethylamine ,98%
2-THIOPHENEMETHYLAMINE, 90+%
Thiophene-2-methanamine
[EINECS(EC#)]

248-639-6
[Molecular Formula]

C5H7NS
[MDL Number]

MFCD00005460
[Molecular Weight]

113.18
[MOL File]

27757-85-3.mol
Chemical PropertiesBack Directory
[Appearance]

Clear yellow liquid
[Boiling point ]

95-99 °C/28 mmHg (lit.)
[density ]

1.103 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.5670(lit.)
[Fp ]

165 °F
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[solubility ]

Easily soluble in ethanol and Chloroform.
[form ]

liquid
[pka]

8.95±0.29(Predicted)
[color ]

Clear colorless to yellow
[Sensitive ]

Air Sensitive
[Detection Methods]

GC
[BRN ]

106296
[InChIKey]

FKKJJPMGAWGYPN-UHFFFAOYSA-N
[CAS DataBase Reference]

27757-85-3(CAS DataBase Reference)
[NIST Chemistry Reference]

2-Thiophenemethanamine(27757-85-3)
[Storage Precautions]

Store under nitrogen
[EPA Substance Registry System]

27757-85-3(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S25:Avoid contact with eyes .
[RIDADR ]

UN 3267 8/PG 2
[WGK Germany ]

3
[Hazard Note ]

Corrosive
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29349990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Sodium hydroxide-->Methanol-->Acetic acid-->Sodium carbonate-->Ammonium hydroxide-->Ammonium chloride-->Formaldehyde-->Hydroxylamine hydrochloride-->ZINC-->Ammonium acetate-->Thiophene-->2-Thiophenecarboxaldehyde
[Preparation Products]

5-(AMINOMETHYL)THIOPHENE-2-SULFONAMIDE-->5-[(ACETYLAMINO)METHYL]THIOPHENE-2-SULFONYL CHLORIDE-->NIH-12848-->tioxazafen-->2-Thienylmethylamine hydrochloride-->2-cyano-N-(2-thienylmethyl)acetamide
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-(Aminomethyl)thiophene(27757-85-3).msds
Hazard InformationBack Directory
[Chemical Properties]

Clear yellow liquid
[Uses]

2-Thiophenemethylamine can be used as areactant involved in synthesis of Triazole-linked-thiopene conjugates and a biomimetic model for studies of metal detoxification and oxidative stress involving metallothionein.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 68, p. 1389, 1946 DOI: 10.1021/ja01211a510
[General Description]

2-Thiophenemethylamine is a potential ligand replacement for poly(3-hexylthiophene)/CdSe hybrid solar cells.
[Purification Methods]

Distil the amine under reduced pressure (nitrogen), from BaO, through a column packed with glass helices. The hydrochloride has m 193-194o (from EtOH/Me2CO) and the picrate has m 181-182o. [Beilstein 18 III/IV 7096.]
Spectrum DetailBack Directory
[Spectrum Detail]

2-Thiophenemethylamine(27757-85-3)1HNMR
2-Thiophenemethylamine(27757-85-3)IR
2-Thiophenemethylamine(27757-85-3)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Thiophenemethylamine, 99%(27757-85-3)
[Alfa Aesar]

2-Thiophenemethylamine, 97%(27757-85-3)
[Sigma Aldrich]

27757-85-3(sigmaaldrich)
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