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ChemicalBook--->CAS DataBase List--->2767-84-2

2767-84-2

2767-84-2 Structure

2767-84-2 Structure
IdentificationMore
[Name]

(1S)-(+)-CAMPHORQUINONE
[CAS]

2767-84-2
[Synonyms]

(1S)-(+)-2,3-BORNANEDIONE
(1S)-2,3-BORNANEDIONE
(1S,4R)-1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTANE-2,3-DIONE
(1S)-(+)-BORNANEDIONE
(1S)-(+)-CAMPHORQUINONE
(+)-2,3-BORNANEDIONE
(+)-CAMPHORQUINONE
CAMPHORQUINONE,-S-(+)-
L-2, 3-BORNANEDIONE
L-(+)-CAMPHORQUINONE
L-CAMPHORQUINONE
S-(+)-CAMPHORQUINONE
3-dione,1,7,7-trimethyl-,(1S)-Bicyclo[2.2.1]heptane-2
7,7-trimethyl-3-dion(1s)-bicyclo[2.2.1]heptane-1
(1S)-1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione
Bicyclo2.2.1heptane-2,3-dione, 1,7,7-trimethyl-, (1S,4R)-
(1S,4β)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2,3-dione
[EINECS(EC#)]

220-446-1
[Molecular Formula]

C10H14O2
[MDL Number]

MFCD00064159
[Molecular Weight]

166.22
[MOL File]

2767-84-2.mol
Chemical PropertiesBack Directory
[Appearance]

YELLOW POWDER
[Melting point ]

197-201 °C(lit.)
[alpha ]

+100° (20/D)(c=1.9, C6H5CH3)
[Boiling point ]

234.44°C (rough estimate)
[density ]

0.9817 (rough estimate)
[refractive index ]

1.4859 (estimate)
[form ]

powder to crystal
[color ]

White to Yellow to Orange
[optical activity]

[α]20/D +100°, c = 1.9 in toluene
[BRN ]

2613999
[CAS DataBase Reference]

2767-84-2(CAS DataBase Reference)
[EPA Substance Registry System]

Bicyclo[2.2.1]heptane-2,3-dione, 1,7,7-trimethyl-, (1S,4R)- (2767-84-2)
Safety DataBack Directory
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[F ]

10
[TSCA ]

Yes
[HS Code ]

29142900
Hazard InformationBack Directory
[Chemical Properties]

YELLOW POWDER
[Uses]

Chiral starting material.
[Definition]

ChEBI: (1S)-bornane-2,3-dione is a bornane-2,3-dione. It is an enantiomer of a (1R)-bornane-2,3-dione.
[Purification Methods]

It can be purified by steam distillation, recrystallisation (yellow prisms) from EtOH, *C6H6 or Et2O/pet ether and it can be sublimed in a vacuum. The (±)-quinone forms needles from EtOH, m 197-198o, 203o. [Buxtorf & Flatt Helv Chim Acta 13 1026 1930, Asahena et al. Chem Ber 67 1432 1934, Beiltein 7 I 325.]
Spectrum DetailBack Directory
[Spectrum Detail]

(1S)-(+)-CAMPHORQUINONE(2767-84-2)1HNMR
(1S)-(+)-CAMPHORQUINONE(2767-84-2)IR
(1S)-(+)-CAMPHORQUINONE(2767-84-2)Raman
(1S)-(+)-CAMPHORQUINONE(2767-84-2)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

D-Camphoroquinone(2767-84-2)
[Alfa Aesar]

(1S)-(+)-Camphorquinone, 98%(2767-84-2)
[Sigma Aldrich]

2767-84-2(sigmaaldrich)
[TCI AMERICA]

(1S)-(+)-Camphorquinone,>96.0%(GC)(2767-84-2)
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