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ChemicalBook--->CAS DataBase List--->27081-10-3

27081-10-3

27081-10-3 Structure

27081-10-3 Structure
IdentificationMore
[Name]

TROPYLIUM TETRAFLUOROBORATE
[CAS]

27081-10-3
[Synonyms]

TROPYLIUM FLUOBORATE
TROPYLIUM TETRAFLUOROBORATE
cycloheptatrienylium,tetrafluoroborate(1-)
Tropyliumtetrafluoroborate,97%
tropylium fluoroborate
Cycloheptatrienylium tetrafluoroborate.
Tropylium tetrafluoroborate 95%
Tropyliumtetrafluoroborate95%
[EINECS(EC#)]

248-214-5
[Molecular Formula]

C7H7BF4
[MDL Number]

MFCD00013402
[Molecular Weight]

177.94
[MOL File]

27081-10-3.mol
Chemical PropertiesBack Directory
[Appearance]

off-white to beige powder
[Melting point ]

~240 °C (dec.)(lit.)
[storage temp. ]

Keep Cold
[solubility ]

Soluble in hot methanol.
[Sensitive ]

Moisture Sensitive
[BRN ]

3574512
[CAS DataBase Reference]

27081-10-3(CAS DataBase Reference)
[EPA Substance Registry System]

Cycloheptatrienylium, tetrafluoroborate(1-) (27081-10-3)
Safety DataBack Directory
[Hazard Codes ]

Xi,C
[Risk Statements ]

R37/38:Irritating to respiratory system and skin .
R34:Causes burns.
[Safety Statements ]

S22:Do not breathe dust .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[RIDADR ]

UN 3261 8/PG 2
[WGK Germany ]

3
[F ]

10-21
[Hazard Note ]

Irritant/Keep Cold/Moisture Sensitive
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29029090
Hazard InformationBack Directory
[Chemical Properties]

off-white to beige powder
[Uses]

Reactant or reagent involved in:
  • Retro-Buchner reactions for synthesis of arylcyclopropanes
  • Desymmetrization for access to homocalystegine analogs or aminocycloheptitols
  • α-Cyanation of imines
  • Stereoselective α-alkylation of aldehydes with stable carbocations
  • Oxidative C-H activation of aliphatic aldehydes
  • Electrochemical Redox transformations
[Uses]

Reactant or reagent involved in:• ;Retro-Buchner reactions for synthesis of arylcyclopropanes1• ;Desymmetrization for access to homocalystegine analogs2 or aminocycloheptitols3• ;α-Cyanation of imines4• ;Stereoselective α-alkylation of aldehydes with stable carbocations5• ;Oxidative C-H activation of aliphatic aldehydes6• ;Electrochemical Redox transformations7
[Uses]

Tropylium Tetrafluoroborate (CAS# 27081-10-3) can be used as an electrolytic solution for electrochemical devices, as well as for protective coatings for selenium electrophotographic plates.
Spectrum DetailBack Directory
[Spectrum Detail]

TROPYLIUM TETRAFLUOROBORATE(27081-10-3)MS
TROPYLIUM TETRAFLUOROBORATE(27081-10-3)1HNMR
TROPYLIUM TETRAFLUOROBORATE(27081-10-3)13CNMR
TROPYLIUM TETRAFLUOROBORATE(27081-10-3)IR1
TROPYLIUM TETRAFLUOROBORATE(27081-10-3)IR2
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Tropylium tetrafluoroborate, 97%(27081-10-3)
[Sigma Aldrich]

27081-10-3(sigmaaldrich)
[TCI AMERICA]

Tropylium Tetrafluoroborate,>98.0%(T)(27081-10-3)
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