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ChemicalBook--->CAS DataBase List--->2687-12-9

2687-12-9

2687-12-9 Structure

2687-12-9 Structure
IdentificationMore
[Name]

Cinnamyl chloride
[CAS]

2687-12-9
[Synonyms]

3-CHLORO-1-PHENYL-1-PROPENE
3-CHLORO-1-PHENYLPROPENE
(3-CHLORO-1-PROPENYL)BENZENE
(3-CHLOROPROPENYL)BENZENE
3-PHENYL-2-PROPENYL CHLORIDE
3-PHENYLALLYL CHLORIDE
AKOS 371
AKOS BBS-00003853
CINNAMYL CHLORIDE
(3-chloro-1-propenyl)-benzen
(3-chloro-prop-1-enyl)-benzene
(3-chloropropenyl)-benzen
[(1E)-3-Chloro-1-propenyl]benzene
1-Phenyl-3-chloro-1-propene
1-Propene, 3-chloro-1-phenyl-
Benzene, (3-chloropropenyl)-
Benzene,(3-chloro-1-propenyl)-
beta-chloromethylstyrene
Propene, 3-chloro-1-phenyl-
r-Chloropropenylbenzene
[EINECS(EC#)]

220-246-4
[Molecular Formula]

C9H9Cl
[MDL Number]

MFCD00000986
[Molecular Weight]

152.62
[MOL File]

2687-12-9.mol
Chemical PropertiesBack Directory
[Appearance]

yellow to yellow-brown liquid
[Melting point ]

-19 °C (lit.)
[Boiling point ]

108 °C/12 mmHg (lit.)
[density ]

1.096 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.584(lit.)
[Fp ]

175 °F
[storage temp. ]

Refrigerator (+4°C)
[form ]

Liquid
[color ]

Yellow to yellow-brown
[Water Solubility ]

0.2 g/L (20 ºC)
[Sensitive ]

Lachrymatory
[BRN ]

741974
[CAS DataBase Reference]

2687-12-9(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzene, (3-chloro-1-propenyl)-(2687-12-9)
[EPA Substance Registry System]

2687-12-9(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T+,C
[Risk Statements ]

R22:Harmful if swallowed.
R26:Very Toxic by inhalation.
R34:Causes burns.
R43:May cause sensitization by skin contact.
R36:Irritating to the eyes.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S27:Take off immediately all contaminated clothing .
[RIDADR ]

UN 1760 8/PG 2
[WGK Germany ]

3
[RTECS ]

CZ0919905
[Hazard Note ]

Corrosive/Lachrymatory
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29039990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Calcium chloride-->Styrene-->4-PHENYL-1,3-DIOXANE-->Methyl cinnamate-->Benzaldehyde-->3-Phenylpropene-3-ol-->3-CHLORO-1-PHENYL-1-PROPANOL-->1,2-Ethanediyl, 1-phenyl- (9CI)-->cis-1,4-Dichloro-2-butene-->Cinnamyl bromide-->Cinnamic acid-->Cinnamyl alcohol
[Preparation Products]

Stugeron-->Cyclopropanemethanol, 2,2-dichloro-3-phenyl--->(3-methoxy-1-propenyl)benzene-->DIPHENYLCYCLOPROPENONE-->4-Penten-2-one, 5-phenyl--->1H-Indole-2,3-dione, 1-(3-phenyl-2-propen-1-yl)-
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Cinnamyl chloride(2687-12-9).msds
Hazard InformationBack Directory
[Chemical Properties]

yellow to yellow-brown liquid
[Uses]

Cinnamyl chloride is used in the enantioselective total synthesis of helioporins C and E, bioactive marine diterpenes.
[General Description]

Cinnamyl chloride reacts regioselectively with aryl and alkenylgold(I) phosphanes in the presence of palladium catalyst in THF to afford the α-substitution product?.
Spectrum DetailBack Directory
[Spectrum Detail]

Cinnamyl chloride(2687-12-9)1HNMR
Cinnamyl chloride(2687-12-9)FT-IR
Cinnamyl chloride(2687-12-9)IR
Cinnamyl chloride(2687-12-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Cinnamyl chloride, 95% trans(2687-12-9)
[Alfa Aesar]

Cinnamyl chloride, 95%, stab. with sodium carbonate(2687-12-9)
[Sigma Aldrich]

2687-12-9(sigmaaldrich)
[TCI AMERICA]

Cinnamyl Chloride,>95.0%(GC)(2687-12-9)
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