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ChemicalBook--->CAS DataBase List--->25037-45-0

25037-45-0

25037-45-0 Structure

25037-45-0 Structure
IdentificationBack Directory
[Name]

POLY(BISPHENOL A CARBONATE)
[CAS]

25037-45-0
[Synonyms]

POLYCARBONATE
CARBONATE RESIN
POLYCARBONATE 326
POLYCARBONATE 46000
POLYCARBONATE RESIN
POLYCARBONATE 6'800
POLYCARBONATE 50'000
POLYCARBONATE 30'600
POLYCARBONATE 20'200
POLYCARBONATE 195'000
Polycarbonate,colored
CARBONATE (POLY) RESIN
PolyCarbonateEster(PC)
bisphenol-a-polycarbonate
POLY(BISPHENOL A CARBONATE)
bisphenol A carbonate polymer
Polycarbonate, flame retarding
POLYCARBONATE STANDARD 326, FOR GPC
POLYCARBONATE STANDARD 3'860 FOR GPC
POLYCARBONATE STANDARD 6'800, FOR GPC
POLYCARBONATE STANDARD 1'590 FOR GPC
POLYCARBONATE STANDARD 10'400 FOR GPC
POLYCARBONATE STANDARD 20'200, FOR GPC
POLYCARBONATE STANDARD 30'600, FOR GPC
POLYCARBONATE STANDARD 50'000 FOR GPC
POLYCARBONATE STANDARD 195'000, FOR GPC
POLYCARBONATE STANDARD 127'000 FOR GPC
POLYCARBONATE RESIN, SECONDARY STANDARD
POLY(BISPHENOL A CARBONATE), MELT INDEX 7
POLY(BISPHENOL A CARBONATE), MELT INDEX 4.5
2,2-Bis(4-hydroxyphenyl)propyl polycarbonate
POLY(BISPHENOL A CARBONATE), MELT INDEX 10-12
Poly[2,2-bis(4-hydroxyphenyl)propanecarbonate]
Polycarbonatesof2,2-bis(4-hydroxyphenyl)propane
POLYCARBONATE RESIN, AVERAGE MW CA. 64,0 00 (GPC)
4,4''-Dihydroxydiphenyl-2,2-propane carbonate polymer
Poly(Bisphenol A carbonate) average Mw ~45,000 by GPC
Carbonicacid,polymerwith4,4’-(1-methylethylidene)bis(phenol)
carbonicacid,polymerwith4,4’-(1-methylethylidene)bis[phenol]
POLYCARBONATE RESIN, SECONDARY STANDARD, MOLECULAR WEIGHT SERIES
Poly(Bisphenol A carbonate) Melt index 10-12 g/10 Min (300C/1.2kg)
[Molecular Formula]

C31H32O7
[MDL Number]

MFCD00084476
[MOL File]

25037-45-0.mol
[Molecular Weight]

290.32
Chemical PropertiesBack Directory
[Melting point ]

220~230℃
[density ]

1.2 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.586
[solubility ]

chlorinated solvents: soluble
[form ]

neat
[Dielectric constant]

2.9(Ambient)
[Uses]

Polycarbonates are plastics widely used in modern industry having good temperature and impact resistance. This plastic is particularly good to work with more conventional definition techniques (injection molding, extrusion into tubes or cylinders and thermoforming). It is also used when optical transparency is needed, having more than 80% transmission up to the 1560-nm range (short wave infrared range). It has moderated chemical resistance properties, being chemically resistant to diluted acids and alcohols. It is poorly resistant against ketones, halogens, and concentrated acids. The major disadvantage associated with polycarbonates is the low glass transition temperature (Tg> 40°C), but it is still largely used as low-cost material in microfluidic systems and also as a sacrificial layer.
[EPA Substance Registry System]

Carbonic acid, polymer with 4,4'-(1-methylethylidene)bis[phenol] (25037-45-0)
Safety DataBack Directory
[WGK Germany ]

3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Chlorine-->Formic acid-->Chloromethane-->METALLURGICAL COKE-->Bisphenol A-->Diphenyl carbonate-->Molecular weight regulator-->Benzyltrimethylammonium chloride
[Preparation Products]

Bisphenol A-->polyethylene conductive plastics-->conductive film
Hazard InformationBack Directory
[Chemical Properties]

Polycarbonate is a polyester in which dihydric (or polyhydric) phenols are joined through carbonate linkages. The general-purpose type of polycarbonate is based on 2,2-bis(4'-hydroxybenzene)propane (bisphenol A) and has the general structure:
Polycarbonate structure
Polycarbonates are the toughest of all thermoplastics. They are window-clear, amazingly strong and rigid, autoclavable, and nontoxic. They have a brittleness temperature of 135℃.
[Definition]

A thermoplastic polymer consisting of polyesters of carbonic acid and dihydroxy compounds. They are tough and transparent, used for making soft-drink bottles and electrical connectors.
[Preparation]

To a solution of 2,2-bis-(4- hydroxyphenyl)propane 909 (0.68 g, 3 mmol) in dichloromethane (10 mL) was added triethylamine (0.60 g, 6 mmol), followed by a solution of triphosgene (0.30 g,1 mmol) in dichloromethane (10 mL). The mixture was stirred for 8 h at room temperature, washed with water (3×) and with aq. sodium hydrogen carbonate solution (3×), and dried over sodium sulfate. The solvent was removed in vacuo and the resulting colorless powder was dried under high vacuum; yield 0.74 g.
[General Description]

Service temperature, max.135°C
Spectrum DetailBack Directory
[Spectrum Detail]

Polycarbonate(25037-45-0)Raman
Polycarbonate(25037-45-0)IR
Polycarbonate(25037-45-0)FT-IR
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