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ChemicalBook--->CAS DataBase List--->2439-99-8

2439-99-8

2439-99-8 Structure

2439-99-8 Structure
IdentificationMore
[Name]

Glyphosine
[CAS]

2439-99-8
[Synonyms]

GLYCINE-N,N-BIS(METHYLENEPHOSPHONIC ACID)
GLYPHOSINE
N-(CARBOXYMETHYL)IMINODI(METHYLPHOSPHINIC ACID)
N,N-BIS(PHOSPHONOMETHYL)GLYCINE
cp41845
n,n-bis(phosphonomethyl)-glycin
Polaris(monsanto)
Glyphosphine
polaris
N,N-bis phophonomethyl glycine
glyphosine (ISO) N,N-bis(phosphonomethyl)glycine
2-(Bis(phosphonomethyl)amino)acetic acid
N,N-Di(phosphonomethyl)glycine
Nitrilomonomethylcarbonyldimethylphosphonic acid
[EINECS(EC#)]

219-468-4
[Molecular Formula]

C4H11NO8P2
[MDL Number]

MFCD00056670
[Molecular Weight]

263.08
[MOL File]

2439-99-8.mol
Chemical PropertiesBack Directory
[Melting point ]

263°C
[Boiling point ]

668.4±65.0 °C(Predicted)
[density ]

1.952±0.06 g/cm3(Predicted)
[storage temp. ]

+2C to +8C
[solubility ]

PBS (pH: 7.2):5.0(Max Conc. mg/mL);19.01(Max Conc. mM)
[form ]

Solid
[pka]

pK1 1.42; pK2 2.10; pK3 5.02; pK4 6.40; pK5 11.19(at 25℃)
[color ]

White
[Water Solubility ]

248g/L(20 ºC)
[Merck ]

13,4526
[BRN ]

1884944
[CAS DataBase Reference]

2439-99-8(CAS DataBase Reference)
[EPA Substance Registry System]

2439-99-8(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R41:Risk of serious damage to eyes.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S2:Keep out of the reach of children .
[RIDADR ]

UN 3261 8/PG 3
[WGK Germany ]

1
[RTECS ]

MB9120000
[HS Code ]

2922.49.8000
[Toxicity]

LD50 orally in rats: 3925 mg/kg; dermally in rabbits: >5010 mg/kg (Ahlrichs)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Phosphorus trichloride-->Glycine-->Propanil-->METHYLPHOSPHONIC ACID-->Glyphosate-->GLYPHOSATE-N-METHYL
[Preparation Products]

PhosphonoMethanol
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Glyphosine(2439-99-8).msds
Hazard InformationBack Directory
[Description]

Glyphosine was introduced in 1973 and is preferably used in sugar beets. The synthesis starting with glycine uses two equivalents of formaldehyde and of phosphorous trichloride under oxidative conditions. A second derivative of Glyphosate is a cyclic phosphaoxazole being formed from Glyphosate and formaldehyde. This compound is claimed to control the growth of some grasses without dis- coloration or phytotoxicity.
[Uses]

Application: Complexing agent; pK-values: pK1: ·2, pK2: 2.0, pK3: 5.20, pK4: 6.77, pK5: 10.89

Anti-diabetic; delay onset of diabetes in non-obese NOD mice

Glyphosine binds to a pocket of MHC class II molecules I-Ag7 and DQ8, and modify T cell responses to the autoantigenic insulin B chain fragment 9–23 (B:9–23) peptide. Glyphosine stimulate IL-10 production and delay onset of diabetes in non-obese NOD mice.?
[Uses]

Chemical ripener; plant growth regulator.
[Definition]

ChEBI: A tertiary amino compound that consists of glycine bearing two N-phosphonomethyl substituents.
[General Description]

N,N-Bis(phosphonomethyl)glycine was present in the ligand bound to human apotransferrin.
[Biochem/physiol Actions]

Anti-diabetic; delay onset of diabetes in non-obese NOD mice
Spectrum DetailBack Directory
[Spectrum Detail]

Glyphosine(2439-99-8)1HNMR
Glyphosine(2439-99-8)13CNMR
Glyphosine(2439-99-8)IR1
Glyphosine(2439-99-8)IR2
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

2439-99-8(sigmaaldrich)
[TCI AMERICA]

Glycine-N,N-bis(methylenephosphonic Acid),>97.0%(T)(2439-99-8)
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