| Identification | More | [Name]
1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE | [CAS]
23978-55-4 | [Synonyms]
1,10-DIAZA-18-CROWN-6
1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE
1,7,10,16-TETRAOXA-4,13-DIAZACYCLOOCTADECANE
4,13-DIAZA-18-CROWN-6
4,13-DIAZA-18-CROWN 6-ETHER
7,16-DIAZA-18-CROWN-6
DIAZA-18-CROWN-6
KRYPTOFIX 22
KRYPTOFIX 22 POLYMER
KRYPTOFIX(R) 22
KRYPTOFIX(R) 22 POLYMER
1,10-diaza-4,7,13,16-tetraoxacyclooctadecane
1,4,10,13-Tetraoza-7,16-diazacyclooctadecane
4,7,13,16-Tetraoxa-1,10-diazacyclo octadecane
7,16-diaza-1,4,10,13-tetraoxcyclooctadecane
cryptand2.2
cryptand22
1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE, >=96%
KRYPTOFIX 22 POLYMER FOR SYNTHESIS
KRYPTOFIX 22 99+% | [EINECS(EC#)]
245-965-0 | [Molecular Formula]
C12H26N2O4 | [MDL Number]
MFCD00005112 | [Molecular Weight]
262.35 | [MOL File]
23978-55-4.mol |
| Chemical Properties | Back Directory | [Appearance]
off-white shiny crystalline powder | [Melting point ]
111-114 °C(lit.) | [Boiling point ]
405.6°C (rough estimate) | [density ]
1.0807 (rough estimate) | [refractive index ]
1.4560 (estimate) | [storage temp. ]
0-6°C | [form ]
Shiny Crystalline Powder | [pka]
9.00±0.20(Predicted) | [color ]
Off-white | [Water Solubility ]
Soluble in water. | [BRN ]
609764 | [CAS DataBase Reference]
23978-55-4(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
2
| [RTECS ]
HM1650000
| [F ]
10 | [HS Code ]
29349990 | [Toxicity]
LD50 orally in Rabbit: 3400 mg/kg |
| Hazard Information | Back Directory | [Chemical Properties]
off-white shiny crystalline powder | [Uses]
1,4,10,13-Tetraoxa-7,16-diazacyclooctadecane is a crown ether, which can be used:
- In the spectroscopic studies of its complex-forming reaction with iodine.
- To prepare the ligand 7,16-bis(5-t-butyl-2-hydroxybenzyl)-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane.
- As a ligand in the study of zirconium facilitated hydrolysis of a dipeptide at neutral pH.
| [Purification Methods]
Twice recrystallise it from *benzene/n-heptane, and dry it for 24hours under high vacuum [Weber & V.gtle Top Curr Chem (Springer Verlag, Berlin) 98 1 1981, D'Aprano & Sesta J Phys Chem 91 2415 1987]. |
| Spectrum Detail | Back Directory | [Spectrum Detail]
1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE(23978-55-4)1HNMR
1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE(23978-55-4)FT-IR
1,4,10,13-TETRAOXA-7,16-DIAZACYCLOOCTADECANE(23978-55-4)IR
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