Identification | Back Directory | [Name]
(+)-Bis[(R)-1-phenylethyl]amine | [CAS]
23294-41-9 | [Synonyms]
(R,R)-Bis-(1-phenylethyl)amin (+)-Bis[(R)-1-phenylethyl]amine (R)-bis((R)-1-phenylethyl)aMine (+)-bis[(r)-α-methylbenzyl]amine (+)-Bis[(R)-1-phenylethyl]amine 99% (+)-BIS (R)-1-PHENYLETHYL!AMINE HYDRO- [R-(R*,R*)]-(+)-Bis(α-methylbenzyl)amine (+)-Bis[(R)-1-phenylethyl]amine, ChiPros (+)-Bis[(R)-1-phenylethyl]amine, 99% (99+% EE/GLC) (+)-Bis[(R)-1-phenylethyl]amine, ChiPros 99%, ee 98+% (+)-Bis[(R)-1-phenylethyl]aMine, ChiPros|r, 99%, ee 98+% Benzenemethanamine, α-methyl-N-[(1R)-1-phenylethyl]-, (αR)- (+)-BIS[(R)-1-PHENYLETHYL]AMINE, OR (R)-BIS((R)-1-PHENYLETHYL)AMINE (+)-Bis[(R)-α-methylbenzyl]amine, [R-(R*,R*)]-(+)-Bis(α-methylbenzyl)amine | [Molecular Formula]
C16H19N | [MDL Number]
MFCD00243088 | [MOL File]
23294-41-9.mol | [Molecular Weight]
225.33 |
Chemical Properties | Back Directory | [Melting point ]
~260 °C
| [alpha ]
199 º (NEAT) | [Boiling point ]
86 °C0.05 mm Hg(lit.)
| [density ]
0.985 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.5523(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [pka]
8.79±0.29(Predicted) | [optical activity]
[α]20/D +199.0°, neat | [Water Solubility ]
Insoluble in water. | [BRN ]
3590931 | [CAS DataBase Reference]
23294-41-9 |
Hazard Information | Back Directory | [Uses]
(+)-Bis[(R)-1-phenylethyl]amine play a very extensive role of making chirally optically active drugs and compounds. Also as intermediates. | [Uses]
(+)-Bis[(R)-1-phenylethyl]amine can be used:
- In the synthesis of?β-amino acids.
- In the preparation of chiral C(19)-C(26) and C(27)-C(32) moieties of scytophycin C.
- To induce enantioselectivity in the deprotonation of prochiral ketones.
- As a starting material for the synthesis of chiral phenolate ligands through Mannich condensation reaction.
- In the synthesis of chiral phosphoramidite ligands.
- To prepare chiral cyclic isoimidium salts, which are further used to synthesize chiral lactones through Diels-Alder reaction.
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Company Name: |
Alfa Aesar
|
Tel: |
400-6106006 |
Website: |
http://chemicals.thermofisher.cn |
Company Name: |
Energy Chemical
|
Tel: |
021-021-58432009 400-005-6266 |
Website: |
http://www.energy-chemical.com |
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