| Identification | More | [Name]
Triallylamine | [CAS]
102-70-5 | [Synonyms]
AMINOTRI-2-PROPENE
N，N-Di-2-propenyl-2-propen-1-Amine
TAA
tri-2-propenylamine
TRIALLYLAMINE
(CH2=CHCH2)3N
n,n-di-2-propenyl-2-propen-1-amin
N,N-Diallyl-2-propen-1-amine
tertiaryamine
Tris(2-propenyl)amine
2-Propen-1-amine, N,N-di-2-propenyl-
TRIALLYLAMINE: 97.5%
TRIALLYAMINE HCL
Tri(prop-1-enyl)amine
Trialkylamine
1,1',1''-Nitrilotri(2-propene) | [EINECS(EC#)]
203-048-2 | [Molecular Formula]
C9H15N | [MDL Number]
MFCD00026093 | [Molecular Weight]
137.22 | [MOL File]
102-70-5.mol |
| Chemical Properties | Back Directory | [Appearance]
dark brown liquid | [Melting point ]
-70°C | [Boiling point ]
150-151 °C (lit.) | [density ]
0.79 g/mL at 25 °C(lit.)
| [vapor density ]
4.73 (vs air)
| [vapor pressure ]
90 mm Hg ( 80 °C)
| [refractive index ]
n20/D 1.451(lit.)
| [Fp ]
87 °F
| [storage temp. ]
2-8°C | [form ]
clear liquid | [pka]
pK1:8.31(+1) (25°C) | [color ]
Colorless to Yellow to Orange | [Stability:]
Stable. Flammable. Incompatible with strong oxidizing agents. | [Water Solubility ]
250 g/100 mL | [InChIKey]
VPYJNCGUESNPMV-UHFFFAOYSA-N | [Uses]
Intermediate. | [CAS DataBase Reference]
102-70-5(CAS DataBase Reference) | [NIST Chemistry Reference]
2-Propen-1-amine, N,N-di-2-propenyl-(102-70-5) | [EPA Substance Registry System]
102-70-5(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R10:Flammable.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R34:Causes burns. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2610 3/PG 3
| [WGK Germany ]
3
| [RTECS ]
XX5950000
| [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29211990 | [Safety Profile]
Poison by skin contact
and intraperitoneal routes. Moderately toxic
by ingestion and inhalation. An eye and
severe skin irritant. Human systemic effects
by inhalation: structural or functional
changes in trachea or bronchi. Flammable
liquid when exposed to heat, flame or
oxidlzers. To fight fire, use foam, alcohol
foam, fog. When heated to decomposition it
emits toxic fumes of NOx. See also AMINES
and ALLYL COMPOUNDS. | [Hazardous Substances Data]
102-70-5(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
A colorless liquid with a fishlike odor. Density 0.800 g/cm3 and insoluble in water. Hence floats on water. Flash point 103°F. Vapors heavier than air. May irritate skin and eyes. Used to make other chemicals. | [Reactivity Profile]
TRIALLYLAMINE(102-70-5) is a strong reducing agent that reacts violently with oxidizing agents. Corrosive towards Al and Zn [Handling Chemicals Safely 1980 p. 912] . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. | [Air & Water Reactions]
Flammable. Insoluble in water. | [Health Hazard]
May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. | [Fire Hazard]
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. | [Chemical Properties]
dark brown liquid | [Chemical Properties]
Triallylamine is a flammble liquid. Triallylamine can be detected at 0.5 ppm and is severely
irritating at 75 ppm. | [Application]
Triallylamine (TAA) reacts with primary aromatic amines in the presence of a ruthenium catalyst to form 2-ethyl-3-methylquinolines.
TAA undergoes hydrozirconation followed by transmetalation with germanium tetrachloride to form 1-aza-5-germa-5-chlorobicyclo[3.3.3]undecane. This compound can react with Grignard or lithium reagents to form the corresponding 5-organo compounds.
The cycloaddition of TAA to fluorinated 1,3,4-oxadiazoles affords octahydro-2,7-methanofuro[3,2-c]pyridines. | [Definition]
ChEBI: Triallylamine is a tertiary amino compound. | [Production Methods]
Triallylamine is manufactured using allyl chloride and
ammonia under heat and pressure. It is used as a solvent
and in organic syntheses. |
|
|