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ChemicalBook--->CAS DataBase List--->2283-08-1

2283-08-1

2283-08-1 Structure

2283-08-1 Structure
IdentificationMore
[Name]

2-HYDROXY-1-NAPHTHOIC ACID
[CAS]

2283-08-1
[Synonyms]

2-HYDROXY-1-NAPHTHOIC ACID
2-NAPHTHOL-1-CARBOXYLIC ACID
AKOS 223-44
LABOTEST-BB LT00452644
RARECHEM AL BE 0092
1-Naphthalenecarboxylic acid, 2-hydroxy-
1-Naphthoic acid, 2-hydroxy-
2-hydroxy-1-naphthalenecarboxylicaci
2-hydroxy-α-naphthoic acid
Methyl 2-hydroxynaphthalene-1-carboxylate
2-Hydroxy-1-naphthalenecarboxylic acid
2-Hydroxynaphthalene-1-carboxylic acid
Hydroxynaphthalene-1-carboxylic acid
Naphthol-1-carboxylic acid
[EINECS(EC#)]

218-919-2
[Molecular Formula]

C11H8O3
[MDL Number]

MFCD00004009
[Molecular Weight]

188.18
[MOL File]

2283-08-1.mol
Chemical PropertiesBack Directory
[Melting point ]

167 °C (dec.) (lit.)
[Boiling point ]

283.17°C (rough estimate)
[density ]

1.2100 (rough estimate)
[refractive index ]

1.6400 (estimate)
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

powder to crystal
[pka]

pK1:3.29;pK2:9.68 (20°C)
[color ]

White to Light red to Green
[BRN ]

975575
[CAS DataBase Reference]

2283-08-1(CAS DataBase Reference)
[EPA Substance Registry System]

1-Naphthalenecarboxylic acid, 2-hydroxy- (2283-08-1)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

2
[TSCA ]

Yes
[HS Code ]

2918199890
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium hydroxide-->1,4-Dioxane-->2-Naphthol
[Preparation Products]

1-Bromo-2-naphthol-->2-METHOXY-1-NAPHTHOIC ACID-->METHYL 2-HYDROXY-1-NAPHTHOATE-->9,11-Dihydroxy-12H-benzo[a]xanthen-12-one
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

β-hydroxy-naphthoic acid(2283-08-1).msds
Hazard InformationBack Directory
[Chemical Properties]

2-Hydroxy-1-naphthoic acid [2283-08-1], C11H8O3, Mr 188.17, has a mp of 156 – 157℃ (decomp. to 2-naphthol and CO2). The monosodium salt is unstable in hot aqueous solution. 2- Hydroxy-1-naphthoic acid is decarboxylated by nitrous acid, forming 1-nitroso-2-naphthol, and by diazo salts, forming a 1-azo-2-naphthol. An ethanolic solution of 2-hydroxy-1-naphthoic acid gives a dark blue color with iron(III) chloride. Chlorosulfonic acid at 30℃ gives the 6-sulfonyl chloride derivative.
[Uses]

?2-Hydroxy-1-naphthoic acid is an intermediate of minor importance in the synthesis of azo dyes.
[Production Methods]

Treatment of the dried sodium or potassium salt of 2-naphthol with carbon dioxide at 120 C under pressure gives an 80 % yield of product after careful work-up. Solvents such as toluene, tetralin, or diphenyl oxide are patented alternatives.
Spectrum DetailBack Directory
[Spectrum Detail]

2-HYDROXY-1-NAPHTHOIC ACID(2283-08-1)MS
2-HYDROXY-1-NAPHTHOIC ACID(2283-08-1)1HNMR
2-HYDROXY-1-NAPHTHOIC ACID(2283-08-1)13CNMR
2-HYDROXY-1-NAPHTHOIC ACID(2283-08-1)IR1
2-HYDROXY-1-NAPHTHOIC ACID(2283-08-1)IR2
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

2-Hydroxy-1-naphthoic acid, 98%(2283-08-1)
[Sigma Aldrich]

2283-08-1(sigmaaldrich)
[TCI AMERICA]

2-Hydroxy-1-naphthoic Acid,>98.0%(T)(2283-08-1)
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