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ChemicalBook--->CAS DataBase List--->22135-49-5

22135-49-5

22135-49-5 Structure

22135-49-5 Structure
IdentificationBack Directory
[Name]

(S)-(-)-1-PHENYL-1-BUTANOL
[CAS]

22135-49-5
[Synonyms]

(1S)-1-phenylbutan-1-ol
(1S)-1-phenyl-1-butanol
(S)-(-)-1-PHENYL-1-BUTANOL
(s)-(-)-α-propylbenzyl alcohol
S(-)-ALPHA-PROPYLBENZYL ALCOHOL
Benzenemethanol, α-propyl-, (αS)-
[Molecular Formula]

C10H14O
[MDL Number]

MFCD00064282
[MOL File]

22135-49-5.mol
[Molecular Weight]

150.22
Chemical PropertiesBack Directory
[Melting point ]

45-47 °C(lit.)
[Boiling point ]

120 °C0.05 mm Hg(lit.)
[density ]

0.9108 (rough estimate)
[refractive index ]

1.5190 (estimate)
[Fp ]

217 °F
[optical activity]

[α]21/D 48.6°, c = 5 in chloroform
[BRN ]

2043698
Safety DataBack Directory
[Safety Statements ]

22-24/25
[WGK Germany ]

3
Spectrum DetailBack Directory
[Spectrum Detail]

(S)-(-)-1-PHENYL-1-BUTANOL(22135-49-5)1HNMR
(S)-(-)-1-PHENYL-1-BUTANOL(22135-49-5)Raman
(S)-(-)-1-PHENYL-1-BUTANOL(22135-49-5)IR
Hazard InformationBack Directory
[Purification Methods]

Purify the alcohol by distillation, and the distllate crystallises on cooling. The hydrochloride has [] 20 +45.1o (c 4.8, *C6H6). The (-)-hydroperoxide has b58o/0.005mm, n D 1.5123,  D -2.14o, (l = 0.5dcm, neat). [Holding & Ross J Chem Soc 145 1954, Davies & Feld J Chem Soc 4637 1958.] The (±)-racemate has b 73o/0.05mm, and its 4-nitrophenylhydrazone has m 58o. [Beilstein 6 IV 3272.]
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