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ChemicalBook--->CAS DataBase List--->22002-45-5

22002-45-5

22002-45-5 Structure

22002-45-5 Structure
IdentificationMore
[Name]

3-BROMO-4-METHOXYTOLUENE
[CAS]

22002-45-5
[Synonyms]

2-BROMO-4-METHYLANISOLE
3-BROMO-4-METHOXYTOLUENE
m-Bromo-p-methoxytoluene
2-Bromo-4-methylanisole 98%
3-Bromo-4-methoxytoluene >
3-Bromo-4-methoxytoluene 98%
1-Methoxy-2-bromo-4-methylbenzene
2-Bromo-4-methyl-1-methoxybenzene
1-Bromo-2-methoxy-5-methylbenzene
2-bromo-1-methoxy-4-methyl-benzen
Benzene, 2-bromo-1-methoxy-4-methyl-
Methyl(2-bromo-4-methylphenyl) ether
3-BROMO-4-METHOXYTOLUENE ISO 9001:2015 REACH
3-Bromo-4-methoxytoluene, 2-Bromo-1-methoxy-4-methylbenzene
[EINECS(EC#)]

244-705-3
[Molecular Formula]

C8H9BrO
[MDL Number]

MFCD00017783
[Molecular Weight]

201.06
[MOL File]

22002-45-5.mol
Chemical PropertiesBack Directory
[Appearance]

Clear colourless to light yellow liquid
[Melting point ]

15.5 °C(lit.)
[Boiling point ]

124-125 °C20 mm Hg(lit.)
[density ]

1.392 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.565(lit.)
[Fp ]

>230 °F
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

liquid
[color ]

Clear, dark yellow to brown
[Specific Gravity]

1.41
[CAS DataBase Reference]

22002-45-5(CAS DataBase Reference)
[EPA Substance Registry System]

2-Bromo-4-methylanisole (22002-45-5)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HazardClass ]

IRRITANT
[HS Code ]

2909309090
Hazard InformationBack Directory
[Chemical Properties]

Clear colourless to light yellow liquid
[Uses]

2-Bromo-4-methylanisole may be used in the synthesis of:
  • 1,6-bis(2-hydroxy-5-methylphenyl)pyridine (H2mdppy)
  • 1,8-dimethoxy-4-methylanthra-quinone
  • ethyl 2-(2-methoxy-5-methylphenyl)-2-methyl-4-oxocyclopentanecarboxylate
It may be used as starting material in the multi-step synthesis of sesquiterpene (±)-herbertenolide.
[Synthesis Reference(s)]

Synthetic Communications, 23, p. 779, 1993 DOI: 10.1080/00397919308009839
[General Description]

2-Bromo-4-methylanisole can be prepared via bromination of 4-methylanisole using poly(4-vinylpyridinium bromochromate).
Spectrum DetailBack Directory
[Spectrum Detail]

3-BROMO-4-METHOXYTOLUENE(22002-45-5)IR1
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

22002-45-5(sigmaaldrich)
[TCI AMERICA]

3-Bromo-4-methoxytoluene,>97.0%(GC)(22002-45-5)
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