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ChemicalBook--->CAS DataBase List--->21190-88-5

21190-88-5

21190-88-5 Structure

21190-88-5 Structure
IdentificationMore
[Name]

6-BROMOPYRIDINE-2-CARBOXYLIC ACID ETHYL ESTER
[CAS]

21190-88-5
[Synonyms]

6-BROMOPYRIDINE-2-CARBOXYLIC ACID ETHYL ESTER
6-BROMOPYRIDINE-2-ETHYL CARBOXYLATE
ETHYL-6-BROMO-2-PYRIDINECARBOXYLATE
ETHYL 6-BROMOPYRIDINE-2-CARBOXYLATE
RARECHEM AL BI 0899
Ethyl 6-bromo-2-piperidinecarboxylate
ETHYL 6-BROMOPICOLINATE
Ethyl 6-bromopyridine-2-carboxylate 98%
METHYL 2-BROMOPYRIDINE-6-CARBOXYLATE
ethyl 6-bromopicolinate,6-bromopyridine-2-ethyl formate
[EINECS(EC#)]

673-818-4
[Molecular Formula]

C8H8BrNO2
[MDL Number]

MFCD04116913
[Molecular Weight]

230.06
[MOL File]

21190-88-5.mol
Chemical PropertiesBack Directory
[Melting point ]

41-42°C
[Boiling point ]

302.7±22.0 °C(Predicted)
[density ]

1.501±0.06 g/cm3(Predicted)
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[form ]

solid
[pka]

-0.89±0.10(Predicted)
[color ]

Off-white
[CAS DataBase Reference]

21190-88-5(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36
[Safety Statements ]

26
[HS Code ]

2933399990
Hazard InformationBack Directory
[Uses]

ethyl 6-bromopicolinate is a model compound for the preliminary screening of dimerization reaction.
[Preparation]

Ethyl 6-bromopicolinate was prepared by monolithiation of 2,6-dibromopyridine followed by a reaction with ethyl formate and subsequently by a reaction with iodine in ethanol (Scheme 57). This three-step procedure furnished the required ethyl 6-bromopicolinate in 45% yield.
Synthesis of Ethyl 6-bromopicolinate
Synthesis of Ethyl 6-bromopicolinate
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