| Identification | More | [Name]
CHLOROTITANIUM TRIISOPROPOXIDE | [CAS]
20717-86-6 | [Synonyms]
CHLOROTIISOPROPOXYTITANIUM
CHLOROTITANIUM(IV) TRIISOPROPOXIDE
CHLOROTITANIUM TRIISOPROPOXIDE
CHLOROTITANIUM TRIISOPROPYLATE
CHLOROTRIISOPROPOXYTITANIUM
CHLOROTRIISOPROPYL ORTHOTITANATE
CHLOROTRIISOPROPYLOXYTITANE
CTT
ORTHOTITANIC ACID TRIISOPROPYL ESTER CHLORIDE
TITANIC ACID TRIISOPROPYL ESTER CHLORIDE
TITANIUM CHLORIDE TRIISOPROPOXIDE
TITANIUM(IV) TRIISOPROPOXY CHLORIDE
Chlorotitanium tri-i-propoxide,
CHLOROTITANIUM TRIISOPROPOXIDE, 1.0M SOL UTION IN HEXANES
Chlorotriisopropoxytitanium(IV), 95%
Titanium Chloride Triisopropoxide, 1.25M in tetrahydrofuran
CHLOROTRIISOPROPYL ORTHOTITANATE (SOLUTION 1 MOL/L IN N-HEXANE)
Chlorotitanium triisopropoxide, 1.0 M solution in dichloromethane
Chlorotitaniumtriisopropoxide,97%
Titanium, chlorotris(2-propanolato)-, (T-4)- | [EINECS(EC#)]
679-414-4 | [Molecular Formula]
C9H21ClO3Ti | [MDL Number]
MFCD00009861 | [Molecular Weight]
260.58 | [MOL File]
20717-86-6.mol |
| Chemical Properties | Back Directory | [Appearance]
Colorless to yellow liquid or low melting solid, | [Melting point ]
35-40 °C | [Boiling point ]
63-66°C 0,1mm | [density ]
1.091 g/mL at 25 °C(lit.)
| [Fp ]
72 °F
| [storage temp. ]
Flammables area | [solubility ]
sol most nonprotic organic solvents, e.g. Et2O, THF, CH2Cl2, toluene, hexanes | [form ]
liquid | [color ]
fused solid to pale yellow | [Specific Gravity]
1.091 | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [Sensitive ]
Moisture Sensitive | [BRN ]
4163222 | [CAS DataBase Reference]
20717-86-6(CAS DataBase Reference) | [EPA Substance Registry System]
Titanium, chlorotris(2-propanolato)-, (T-4)- (20717-86-6) |
| Safety Data | Back Directory | [Hazard Codes ]
C,F | [Risk Statements ]
R10:Flammable.
R34:Causes burns.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R11:Highly Flammable. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S27:Take off immediately all contaminated clothing .
S16:Keep away from sources of ignition-No smoking . | [RIDADR ]
UN 2924 3/PG 2
| [WGK Germany ]
3
| [F ]
3-10-21 | [TSCA ]
No | [HazardClass ]
4.1 | [PackingGroup ]
II | [HS Code ]
29051990 |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless to yellow liquid or low melting solid, | [Uses]
Chlorotriisopropoxytitanium(IV) solution may be used as a precursor for the synthesis of ultralow density ceramic materials. The product may be used to mediate a reductive amination reaction of 5α-cholestane-3,7-dione to yield aryl aminocholestanes. | [Synthesis Reference(s)]
1. Reetz, M. T.; Westermann, J.; Steinbach, R.; Wenderoth, B.; Peter, R.; Ostarek, R.; Maus, S. CB 1985, 118, 1421.
| [reaction suitability]
core: titanium
reagent type: catalyst | [Synthesis]
Chlorotitanium triisopropoxide can be easily made from a 3:1 mixture of Titanium Tetraisopropoxide and Titanium(IV) Chloride,1 which can be distilled to give the pure reagent or used in situ.
| [Purification Methods]
When distilled under vacuum, the distillate sets slowly to a solid on standing. Stock reagents are made by dissolving the warm liquid in pentane, toluene, Et2O, THF, CH2Cl2,, and can be stored in a pure state or in solution under dry N2 for several months. The reagent is hygroscopic and is hydrolysed by H2O. [Reetz et al. Chem Ber 118 1421 1985.] | [Precautions]
Chlorotitanium triisopropoxide is corrosive; moisture sensitive; flammable liquid; can be stored under nitrogen, in pure form or in solution, for months.
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