| Identification | More | [Name]
BORANE-TRIPHENYLPHOSPHINE COMPLEX | [CAS]
2049-55-0 | [Synonyms]
BORANE-TRIPHENYLPHOSPHINE
BORANE-TRIPHENYLPHOSPHINE COMPLEX
TRIPHENYLPHOSPHINE BORANE | [Molecular Formula]
C18H18BP | [MDL Number]
MFCD00012427 | [Molecular Weight]
276.12 | [MOL File]
2049-55-0.mol |
| Chemical Properties | Back Directory | [Appearance]
white crystals with an unpleasant smell | [Melting point ]
189-191 °C (lit.) | [storage temp. ]
Refrigerator | [form ]
Powder | [color ]
White | [Stability:]
Stable. Incompatible with acids, oxidizing agents, acid chlorides, alcohols. May decompose on exposure to air and moisture. | [Sensitive ]
Air & Moisture Sensitive | [CAS DataBase Reference]
2049-55-0(CAS DataBase Reference) |
| Hazard Information | Back Directory | [Chemical Properties]
white crystals with an unpleasant smell | [Uses]
Reactant for:
- C-P cross coupling with aryl iodides
- Synthesis of N-heterocyclic carbene borane complexes via Lewis base exchange
- Catalyst-free alcoholysis to deprotect phosphane-boranes
- Undergoing heterolytic activation
- Deprotection via reactions with resin-supported amines
- Insertion of overcrowded silylene into hydroboranes
|
|
|