| Identification | More | [Name]
Tetrabutylammonium perchlorate | [CAS]
1923-70-2 | [Synonyms]
TETRABUTYLAMMONIUM PERCHLORATE
TETRA-N-BUTYLAMMONIUM PERCHLORATE
n,n,n-tributyl-1-butanaminiuperchlorate
TETRABUTYLAMMONIUM PERCHLORATE ELECTRO-C HEMICAL GRADE
Tetrabutylammonium perchlorate, contains max. 10% water, 99%
TETRABUTYLAMMONIUM PERCHLORATE REAGENT
Tetrabutylammoniumperchlorate,min.98%
1-Butanaminium, N,N,N-tributyl-, perchlorate
tetra-n-butylammonium perchlorate, electrochemical grade
Tetra-n-butylammonium perchlorate, 99+%
Tetrabutylazanium perchlorate
Tetrabutylammonium perchlorate, min. 98%
Tetrabutylammonium perchlorate, 99%, contains max. 10% water
Tetrabutylaminium·perchlorate
Hyperchloric acidanion·tetrabutylaminium
Tetrabutylaminium·hyperchloric acidanion | [EINECS(EC#)]
217-655-5 | [Molecular Formula]
C16H36ClNO4 | [MDL Number]
MFCD00038722 | [Molecular Weight]
341.91 | [MOL File]
1923-70-2.mol |
| Chemical Properties | Back Directory | [Appearance]
white powder | [Melting point ]
211-215 °C | [density ]
1.0387 (rough estimate) | [refractive index ]
1.6800 (estimate) | [solubility ]
acetonitrile: 0.1 g/mL, clear, colorless
| [form ]
Crystalline Powder | [color ]
White | [Stability:]
Stable. Strong oxidizer-contact with combustible material may cause fire. Incompatible with strong reducing agents, combustible materials. Do not heat. | [Water Solubility ]
Soluble in acetonitrile and ethanol. Very slightly soluble in water. | [Sensitive ]
Hygroscopic | [BRN ]
3579274 | [CAS DataBase Reference]
1923-70-2(CAS DataBase Reference) | [EPA Substance Registry System]
1923-70-2(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
O,Xi | [Risk Statements ]
R5:Heating may cause an explosion.
R8:Contact with combustible material may cause fire.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S17:Keep away from combustible material .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
UN 1479 5.1/PG 2
| [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
5.1 | [PackingGroup ]
II | [HS Code ]
28299000 |
| Hazard Information | Back Directory | [Chemical Properties]
white powder | [Uses]
Tetrabutylammonium perchlorate is a tetraalkylammonium salt that can be used in phase-transfer catalysis. | [Uses]
Suitable for use as a polarographic supporting electrolyteTetra-n-butylammonium perchlorate is used as a supporting electrolyte in polarographic measurements. | [Uses]
Tetrabutylammonium perchlorate is a polarographic supporting electrolyte. | [General Description]
| [reaction suitability]
reagent type: oxidant | [Purification Methods]
Crystallise the perchlorate from EtOH ethyl acetate, from n-hexane or diethyl ether/acetone mixture, ethyl acetate or hot CH2Cl2. Dry it in a vacuum at room temperature over P2O5 for 24hours. [Anson et al. J Am Chem Soc 106 4460 1984, Ohst & Kochi J Am Chem Soc 108 2877 1986, Collman et al. J Am Chem Soc 108 2916 1986, Blau & Espenson J Am Chem Soc 108 1962 1986, Gustowski et al. J Am Chem Soc 108 1986, Ikezawa & Kutal J Org Chem 52 3299 1987, Beilstein 4 IV 557.] |
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