| Identification | More | [Name]
(S,S)-2,3-Butanediol | [CAS]
19132-06-0 | [Synonyms]
2,3-BUTANEDIOL, [S-(R*,R*)]-
(2S,3S)-(+)-2,3-BUTANEDIOL
(2S,3S)-2,3-BUTANEDIOL
L(+)-2,3-BUTANEDIOL
(S,S)-(+)-2,3-BUTANEDIOL
(S,S)-2,3-BUTANEDIOL
(S,S)-(+)-2,3-BUTYLENE GLYCOL
(S,S)-(+)-2,3-DIHYDROXYBUTANE
(S-(R,R))-butane-2,3-diol
(2S,3S)-(+)-2,3-BUTANEDIOL, 97%(99% EE/GLC)
2S,3S-(+)-Butanediol
(2S,3S)-(+)-2,3-Butanediol,99%
(2S,3S)-(+)-2,3-BUTANEDIOL 99%
(S,S)-Butane-2,3-diol
(2S,3S)-Butane-2,3-diol
L-Butane-2,3-diol | [Molecular Formula]
C4H10O2 | [MDL Number]
MFCD00063648 | [Molecular Weight]
90.12 | [MOL File]
19132-06-0.mol |
| Chemical Properties | Back Directory | [Appearance]
SLIGHTLY YELLOW OILY LIQUID | [Melting point ]
20°C | [alpha ]
13 º (c=neat) | [Boiling point ]
179-182 °C (lit.) | [density ]
0.992 g/mL at 20 °C(lit.)
| [refractive index ]
n20/D 1.433
| [Fp ]
185 °F
| [storage temp. ]
2-8°C
| [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Oily Liquid | [pka]
14.67±0.20(Predicted) | [color ]
Slightly yellow | [Specific Gravity]
0.987 | [PH]
9-10 (500g/l, H2O, 20℃) | [explosive limit]
3.1-11.4%(V) | [optical activity]
[α]20/D +13°, neat | [Water Solubility ]
soluble | [BRN ]
1718899 | [Stability:]
hygroscopic | [LogP]
-0.655 (est) | [CAS DataBase Reference]
19132-06-0(CAS DataBase Reference) | [NIST Chemistry Reference]
2,3-Butanediol, [S-(R*,R*)]-(19132-06-0) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Safety Statements ]
S24/25:Avoid contact with skin and eyes . | [RIDADR ]
NA 1993 / PGIII | [WGK Germany ]
3
| [HS Code ]
29053995 |
| Questions And Answer | Back Directory | [Description]
2, 3-Butanediol, which is very important for a variety of chemical feedstocks and liquid fuels, can be derived from the bioconversion of natural resources1-2. It may be used in the production of antifreeze solvents, extraction solvents, butadiene, polymers, polyurethane and diacetyl and may also be used as a fuel1, 2. It can be used as a precursor in the manufacture of a range of chemical products, various plastics and pesticides, including the solvents methyl ethyl ketone (MEK), gamma-butyrolactone (GBL), and 1, 3-butadiene3. Methyl ethyl ketone can be used as a liquid fuel additive. Many other derivatives for potential uses as antifreeze agent (levo-form of 2,3 BDL), solvents, and plastic can also be prepared from 2.3-BDL. Furthermore, it can be added as a flavoring agent in food products when converted to a diacetyl by dehydrogenation2. Nowadays, it has been more and more applied of microbial fermentation for the production of 2.3-BDL2,4.
| [Reference]
- https://www.sigmaaldrich.com/catalog/product/sial/18967?lang=en®ion=US
- Lee, Jinwon, et al. "Biological production of 2,3-butanediol." Applied Microbiology & Biotechnology 55.1(2001):10-8.
- https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3147483/
- Oliver, John W. K., et al. "Cyanobacterial conversion of carbon dioxide to 2, 3-butanediol. PNAS 110.4(2013):1249-1254.
|
| Hazard Information | Back Directory | [Chemical Properties]
SLIGHTLY YELLOW OILY LIQUID | [Uses]
(S,S)-2,3-Butanediol is the (S,S)-isomer of 2,3-Butanediol (B690020), a naturally occurring compound found in cocoa butter. | [Definition]
ChEBI: The (S,S) diastereoisomer of butane-2,3-diol. | [General Description]
L-(+)-2,3-Butanediol is a stereoisomer of 2,3-Butanediol (2,3-BD). 2,3-BD may be used in the production of antifreeze solvents, extraction solvents, butadiene, polymers, polyurethane and diacetyl and may also be used as a fuel. | [Purification Methods]
Purify it by fractional distillation. The bis-(4-nitrobenzoate) has m 141-142o and [] (-) or (+) 52o (c 4 CHCl3). [Ghirardelli & Lucas J Am Chem Soc 79 734 1957, Rubin et al. J Am Chem Soc 74 425 1952, Neish Can J Res 27 6 1949, Neish & Ledingham Can J Res 27 694 1949, Beilstein 1 IV 2524-2525.] |
| Spectrum Detail | Back Directory | [Spectrum Detail]
(S,S)-2,3-Butanediol(19132-06-0)MS
(S,S)-2,3-Butanediol(19132-06-0)1HNMR
(S,S)-2,3-Butanediol(19132-06-0)13CNMR
(S,S)-2,3-Butanediol(19132-06-0)IR1
(S,S)-2,3-Butanediol(19132-06-0)Raman
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