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ChemicalBook--->CAS DataBase List--->18063-03-1

18063-03-1

18063-03-1 Structure

18063-03-1 Structure
IdentificationMore
[Name]

2,6-Difluorobenzamide
[CAS]

18063-03-1
[Synonyms]

2,6-DIFLUOROBENZAMIDE
2,6-difluoro-benzamid
2,6-difluorobenzaminde
2,6-difluorobenzoic acid amide
2,6-Difluorobenzamide97%
2,6-Difluorbenzamid
2,6-Difluorobenzoylamide
2,6-DIFLUOROBENZAMIDE, 98+%
[EINECS(EC#)]

241-972-8
[Molecular Formula]

C7H5F2NO
[MDL Number]

MFCD00007972
[Molecular Weight]

157.12
[MOL File]

18063-03-1.mol
Chemical PropertiesBack Directory
[Appearance]

white powder
[Melting point ]

145-148 °C (lit.)
[Boiling point ]

51-52C/15Tor
[density ]

1,199g/cm
[refractive index ]

1,508
[storage temp. ]

Sealed in dry,Room Temperature
[solubility ]

ethanol: soluble5%, clear to turbid, colorless to light yellow
[form ]

Solid
[pka]

14.54±0.50(Predicted)
[color ]

Off-White
[BRN ]

2047480
[InChIKey]

AVRQBXVUUXHRMY-UHFFFAOYSA-N
[LogP]

0.011-0.25 at 25℃
[CAS DataBase Reference]

18063-03-1(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzamide, 2,6-difluoro-(18063-03-1)
[EPA Substance Registry System]

18063-03-1(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R20:Harmful by inhalation.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
S36/37:Wear suitable protective clothing and gloves .
[WGK Germany ]

1
[RTECS ]

CV4355050
[Hazard Note ]

Irritant
[HazardClass ]

IRRITANT
[HS Code ]

29242990
[Toxicity]

rat,LC50,inhalation,> 2100mg/m3/4H (2100mg/m3),National Technical Information Service. Vol. OTS0543293,
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Potassium fluoride-->2,6-Difluorobenzonitrile-->2,6-Difluorobenzoic acid
[Preparation Products]

Chlorfluazuron-->Hexaflumuron-->Flufenoxuron-->Teflubenzuron-->2,6-Difluoroaniline-->2,6-Difluorobenzoyl isocyanate-->Diflubenzuron-->4-Amino-2,6-difluorophenol-->2,6-Difluoro-4-nitrophenol
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2,6-Difluorobenzamide(18063-03-1).msds
Hazard InformationBack Directory
[Description]

2,6-Difluorobenzamide is a major metabolite of pesticide diflubenzuron and has been quantitated by HPLC/diode-array method.
[Chemical Properties]

white powder
[Uses]

2,6-Difluorobenzamide (CAS# 18063-03-1) is a useful building block used in the synthesis of (E)-3-methyleneisoindolin-1-ones via oxidative annulation acrylates. It is also used in the synthesis of pesticide intermediates, which can be used to produce various insecticides such as fluazuron, chlorpyrifos, and pyrethroids.
[Preparation]

2,6-Difluorobenzamide is obtained by hydrolysis of 2,6-difluorobenzonitrile.
[General Description]

2,6-Difluorobenzamide is a major metabolite of pesticide diflubenzuron and has been quantitated by HPLC/diode-array method.
[Toxics Screening Level]

The Initial Threshold Screening Level (ITSL) for 2,6-Difluorobenzamide is 11 μg/m3 based on an annual averaging time.
[References]

[1] Straniero V, et al. 2,6-Difluorobenzamide inhibitors of the bacterial cell division protein FtsZ: design, synthesis and Structure Activity Relationship study. ChemMedChem, 2017; 12: 1303-1318.
Spectrum DetailBack Directory
[Spectrum Detail]

2,6-Difluorobenzamide(18063-03-1)MS
2,6-Difluorobenzamide(18063-03-1)1HNMR
2,6-Difluorobenzamide(18063-03-1)13CNMR
2,6-Difluorobenzamide(18063-03-1)IR1
2,6-Difluorobenzamide(18063-03-1)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2,6-Difluorobenzamide, 97%(18063-03-1)
[Alfa Aesar]

2,6-Difluorobenzamide, 98+%(18063-03-1)
[Sigma Aldrich]

18063-03-1(sigmaaldrich)
[TCI AMERICA]

2,6-Difluorobenzamide,>95.0%(T)(18063-03-1)
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