| Identification | More | [Name]
3-(METHYLTHIO)ANILINE | [CAS]
1783-81-9 | [Synonyms]
3-AMINOTHIOANISOLE
3-(METHYLMERCAPTO)ANILINE
3-(METHYLTHIO)ANILINE
AKOS 91141
M-AMINOTHIOANISOLE
M-(METHYLTHIO)ANILINE
M-THIOANISIDINE
3-(Methylsulfanyl)aniline
3-(methylthio)-benzenamin
3-(methylthio)benzenamine
3-Methylthio
3-Methylthiobenzenamine
Aniline, 3-methylthio-
Aniline, m-(methylthio)-
Benzenamine, 3-(methylthio)-
m-(methylthio)-anilin
m-Aminophenyl methyl sulfide
m-aminophenylmethylsulfide
3-Aminothioanisole/Meta-(Methylthio)aniline
3-Aminothioanisole~3-(Methylmercapto)aniline | [EINECS(EC#)]
217-232-5 | [Molecular Formula]
C7H9NS | [MDL Number]
MFCD00007793 | [Molecular Weight]
139.22 | [MOL File]
1783-81-9.mol |
| Chemical Properties | Back Directory | [Appearance]
clear dark brown liquid | [Boiling point ]
163-165 °C16 mm Hg(lit.) | [density ]
1.13 g/mL at 25 °C(lit.)
| [vapor pressure ]
1.66Pa at 25℃ | [refractive index ]
n20/D 1.637(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [form ]
clear liquid | [pka]
3.96±0.10(Predicted) | [color ]
Colorless to Light orange to Yellow | [Specific Gravity]
1/130 | [Detection Methods]
GC,NMR | [BRN ]
2078599 | [LogP]
1.68 | [Uses]
Pharmaceutical intermediate. | [CAS DataBase Reference]
1783-81-9(CAS DataBase Reference) | [NIST Chemistry Reference]
3-CH3SC6H4NH2(1783-81-9) | [EPA Substance Registry System]
1783-81-9(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
UN 2810 6.1/PG 3
| [WGK Germany ]
3
| [RTECS ]
BY6301000
| [F ]
2-8-13 | [Hazard Note ]
Harmful | [TSCA ]
T | [HazardClass ]
6.1 | [HazardClass ]
IRRITANT, STENCH | [HS Code ]
29309090 | [Toxicity]
LD50 orl-qal: 750 mg/kg AECTCV 12,355,83 |
| Hazard Information | Back Directory | [Hazard]
See aniline. | [Chemical Properties]
clear dark brown liquid | [Safety Profile]
Moderately toxic by ingestion.When heated to decomposition it emits toxic vapors ofNOx and SOx. | [Purification Methods]
Purify the aniline by fractional distillation in an inert atmostphere. It has UV max at 226 and 300nm. [Bordwell & Cooper J Am Chem Soc 74 10581952.] The N-acetyl derivative has m 78-78.5o (from aqueous EtOH). The hydrochloride has m 260-261o (aqueous EtOH/HCl) or m 225-227o (EtOH/Et2O). [Beilstein 13 H 533, 13 III 1221, 13 IV 1289.] |
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