Identification | Back Directory | [Name]
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) | [CAS]
174813-82-2 | [Synonyms]
[(R,R)-TsDPEN-Ru(Mesitylene)Cl] Chloro[(1R,2R)-N-(p-toluenesulfonyl)-1,2-diphenylethanediamine](mesitylene)ruthenium(II) Chloro[[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido](mesitylene)ruthenium(II) [R-(R*,R*)]-[N-(2-Amino-1,2-diphenylethyl)-4-methylbenzenesulfonamidato-N,N']chloro[(1,2,3,4,6-η)-1,3,5-trimethylbenzene]ruthenium Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(Mesitylene)rutheniuM(II),90% RuCl[(R,R)-Tsdpen(Mesitylene) Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}( mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene) | [Molecular Formula]
C30H30ClN2O3RuS- | [MDL Number]
MFCD12545951 | [MOL File]
174813-82-2.mol | [Molecular Weight]
635.159 |
Hazard Information | Back Directory | [Uses]
RuCl[(R,R)-TsDPEN](mesitylene) may be used as a catalyst to synthesize:
- (2R,3S)-4-Benzyl-2-(hydroxyphenylmethyl)morpholin-3-one from racemic N-benzyl-2-benzoyl-3-morpholinone via dynamic kinetic resolution-based asymmetric transfer hydrogenation (ATH).
- Chiral nonracemic δ-phenylseleno alcohols from δ-phenylseleno ketones via catalytic ATH reaction.
|
|
|