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ChemicalBook--->CAS DataBase List--->17252-51-6

17252-51-6

17252-51-6 Structure

17252-51-6 Structure
IdentificationMore
[Name]

4,4'-Trimethylenedipyridine
[CAS]

17252-51-6
[Synonyms]

1,3-DI-4-PYRIDINOPROPANE
1,3-DI(4-PYRIDYL)PROPANE
4,4'-TRIMETHYLENEDIPYRIDINE
LABOTEST-BB LT00451956
4,4’-(1,3-propanediyl)bis-pyridin
4,4’-(1,3-propanediyl)bis-Pyridine
Dipyridylpropane
4,4'-(propane-1,3-diyl)dipyridine
,3-di(4-pyridyl)propane
Pyridine,4,4'-(1,3-propanediyl)bis-
1,3-Bis(4-pyridyl)propane
4,4'-(Propane-1,3-diyl)bis(pyridine)
4,4'-Trimethylenebispyridine
[EINECS(EC#)]

241-284-8
[Molecular Formula]

C13H14N2
[MDL Number]

MFCD00038046
[Molecular Weight]

198.26
[MOL File]

17252-51-6.mol
Chemical PropertiesBack Directory
[Melting point ]

57-60 °C(lit.)
[Boiling point ]

142°C 2mm
[density ]

1.066±0.06 g/cm3(Predicted)
[Fp ]

142°C/2mm
[storage temp. ]

Inert atmosphere,Room Temperature
[Water Solubility ]

Slightly soluble in water
[form ]

crystal
[pka]

6.30±0.10(Predicted)
[color ]

light yellow
[Sensitive ]

Hygroscopic
[BRN ]

150231
[CAS DataBase Reference]

17252-51-6(CAS DataBase Reference)
[EPA Substance Registry System]

17252-51-6(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

2811
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[HS Code ]

29333990
Hazard InformationBack Directory
[Chemical Properties]

Light yellow crystal
[Uses]

4,4′-Trimethylenedipyridine was used as ligand to study the solvent effects on the formal potential of redox-active self-assembling system [Os(bpy)2(dipy)Cl]1+ (bpy= 2,2′-bipyridine, dipy= 4,4′-Trimethylenedipyridine) in different organic solvents and aqueous solutions. It was used in the synthesis of two- and three-dimensional cadmium-organic frameworks.
[Solubility in organics]

Soluble in Methanol
[Purification Methods]

Crystallise the propane from n-hexane/*benzene (5:1) or Me2CO. The picrate has m 185-185o.[Jampolsky et al. J Am Chem Soc 74 5222 1952, Chow & Fouss J Am Chem Soc 80 1095 1958, Beilstein 23 III/IV 1400.]
Spectrum DetailBack Directory
[Spectrum Detail]

4,4'-Trimethylenedipyridine(17252-51-6)1HNMR
4,4'-Trimethylenedipyridine(17252-51-6)13CNMR
4,4'-Trimethylenedipyridine(17252-51-6)IR1
4,4'-Trimethylenedipyridine(17252-51-6)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

1,3-Di(4-pyridyl)propane, 98%(17252-51-6)
[Sigma Aldrich]

17252-51-6(sigmaaldrich)
[TCI AMERICA]

1,3-Di(4-pyridyl)propane,>97.0%(GC)(17252-51-6)
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