Identification | Back Directory | [Name]
Lithium Bis(fluorosulfonyl)imide | [CAS]
171611-11-3 | [Synonyms]
LiFSI LiFSA ithium Bis(fL Li[(FSO2)2N]LiFSI Lithium bisfluorosulfonimide LithiuM bis(fluorosulfony)iMide Lithium bis(fluorosulfonyl)imide Bis(fluorosulfonyl)imide Lithium bis (fluorosulfonyl) imine lithium Imidodisulfuryl fluoride lithium salt LITHIUM BIS (FLUOROSULFONYL) IMIDE/LiFSi Imidodisulfuryl fluoride lithium salt (LiFSI) Lithium Bis(fluorosulfonyl)imide ISO 9001:2015 REACH LiFSI Lithium Bis(fluorosulfonyl)imide | [EINECS(EC#)]
686-526-7 | [Molecular Formula]
F2NO4S2.Li | [MDL Number]
MFCD28126786 | [MOL File]
171611-11-3.mol | [Molecular Weight]
187.072 |
Chemical Properties | Back Directory | [Melting point ]
124-128℃ | [density ]
1.052g/cm3 at 25℃ | [vapor pressure ]
27.198-31.064Pa at 20-25℃ | [storage temp. ]
Inert atmosphere,2-8°C | [Water Solubility ]
Soluble in water | [form ]
Solid | [color ]
White to Almost white | [InChI]
InChI=1S/F2NO4S2.Li/c1-8(4,5)3-9(2,6)7;/q-1;+1 | [InChIKey]
HOQSGMWVPMHPSZ-UHFFFAOYSA-N | [SMILES]
[N-](S(=O)(F)=O)S(=O)(F)=O.[Li+] | [LogP]
3 at 20℃ and pH6 | [EPA Substance Registry System]
Imidodisulfuryl fluoride, lithium salt (1:1) (171611-11-3) |
Hazard Information | Back Directory | [Chemical Properties]
White to Almost white powder to crystal with Molecular Crystal Electrolytes with High Lithium Ion Conductivity. | [Characteristics]
Lithium bis(fluorosulfonyl)imide(LiFSI) is a important high-performance electrolyte material in new energy devices such as lithium-ion batteries and supercapacitors. It has the advantages of high stability (no decomposition below 200°C), excellent low temperature performance, good hydrolytic stability and environmental friendliness, etc., as the next generation of lithium hexafluorophosphate electrolyte lithium salt for secondary lithium ion batteries. | [Uses]
Lithium Bis(fluorosulfonyl)imide is a useful research chemical. | [Preparation]
Lithium bis(fluorosulfonyl)imide (LiFSI) was synthesized by a metathesis reaction between KFSI and LiBF4 in DMC in nearly quantitative yield, similar to the preparation of its analogue, lithium (fluorosulfonyl) (pentafluoroethanesulfonyl)imide (LiFPFSI). DOI: https://doi.org/10.1016/j.jpowsour.2010.12.040 |
|
|