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ChemicalBook--->CAS DataBase List--->168106-25-0

168106-25-0

168106-25-0 Structure

168106-25-0 Structure
IdentificationBack Directory
[Name]

Zinc bis(trifluoromethylsulfonyl)imide, min. 97%
[CAS]

168106-25-0
[Synonyms]

Zn(NTf2)2
Zinc bis(trifluoroMethylsulfonyl)iMide
Zinc di[bis(trifluoromethylsulfonyl)imide]
Zinc(II) Bis(trifluoromethanesulfonyl)imide
Zinc bis(trifluoromethylsulfonyl)imide, min. 97%
[Molecular Formula]

C4F12N2O8S4Zn
[MDL Number]

MFCD16621474
[MOL File]

168106-25-0.mol
[Molecular Weight]

625.65
Chemical PropertiesBack Directory
[Melting point ]

143-147℃
[Fp ]

>110°(230°F)
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

It is soluble in CH2Cl2 and H2O.
[form ]

Powder
[color ]

white
[Sensitive ]

Moisture Sensitive
[Stability:]

hygroscopic
[CAS DataBase Reference]

168106-25-0
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[RIDADR ]

UN 1759 8/PG II
[WGK Germany ]

3
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

2935909099
Questions And AnswerBack Directory
[Reaction]

  1. Useful catalyst for the Diels-Alder reaction.
  2. Excellent catalyst for the Friedel-Crafts acylations in ionic liquids, or solvent free.
  3. Active catalyst for the ring-opening of cyclopropanes.
  4. Used in the asymmetric Friedel-Crafts reaction of pyrroles and acrylates. 
Reactions of 168106-25-0
Hazard InformationBack Directory
[Uses]

Zinc bis(trifluoromethylsulfonyl)imide is used as a Catalyst for Enantioselective Friedel-Crafts alkylation of pyrroles with β-CF3 acrylates, Stereoselective Diels-Alder reaction, Tandem cyclopropane ring-opening / Conia-ene cyclization Aromatic nitration.
[reaction suitability]

core: zinc
reagent type: catalyst
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