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ChemicalBook--->CAS DataBase List--->16627-71-7

16627-71-7

16627-71-7 Structure

16627-71-7 Structure
IdentificationMore
[Name]

1H,1H,5H-Perfluoropentyl-1,1,2,2-tetrafluoroethylether
[CAS]

16627-71-7
[Synonyms]

1H,1H,5H-OCTAFLUOROPENTYL-1,1,2,2-TETRAFLUOROETHYL ETHER
1H,1H,5H-PERFLUOROPENTYL-1,1,2,2-TETRAFLUOROETHYL ETHER
1H,4H,4H,8H-PERFLUORO-3-OXAOCTANE
2,2,3,3,4,4,5,5-OCTAFLUORO-1-(1,1,2,2-TETRAFLUORO-ETHOXY)PENTANE
1H,
1,1,2,2,3,3,4,4-Oktafluoro-5-(1,1.2,2-tetrafluoroethoxy)pentane
1H,1H,5H-Octafluoropentyl-1,1,2,2-tetrafluoroethyl
[Molecular Formula]

C7HF15O
[MDL Number]

MFCD00155904
[Molecular Weight]

386.06
[MOL File]

16627-71-7.mol
Chemical PropertiesBack Directory
[Boiling point ]

133 °C
[density ]

1.532±0.06 g/cm3(Predicted)
[refractive index ]

1.30
[form ]

clear liquid
[color ]

Colorless to Almost colorless
[InChI]

InChI=1S/C7H4F12O/c8-2(9)5(14,15)7(18,19)4(12,13)1-20-6(16,17)3(10)11/h2-3H,1H2
[InChIKey]

ZNBGTBKGFZMWKR-UHFFFAOYSA-N
[SMILES]

C(F)(F)C(F)(F)C(F)(F)C(F)(F)COC(F)(F)C(F)F
[CAS DataBase Reference]

16627-71-7(CAS DataBase Reference)
[EPA Substance Registry System]

1H,1H,5H-Perfluoropentyl-1,1,2,2-tetrafluoroethylether (16627-71-7)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[RIDADR ]

UN 3271 3/PG III
[Hazard Note ]

Irritant
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

2909199090
Hazard InformationBack Directory
[Chemical Properties]

Colorless to Almost colorless clear liquid.
[Uses]

1H,1H,5H-Perfluoropentyl-1,1,2,2-tetrafluoroethylether can be used as organic synthesis intermediates and pharmaceutical intermediates, mainly used in laboratory research and development processes and chemical production processes.
[Preparation]

In a 2L pressure reactor, add 600g sulfolane, 620g difluoroacetic acid-2,2,3,3,4,4,5,5-octafluoropentyl ester, 200g tetramethylammonium hydroxide, and replace the inside of the kettle with nitrogen Turn on the stirring, heat up to 50°C, pass in tetrafluoroethylene, and maintain the pressure at 0.3MPa for reaction. When the tetrafluoroethylene has reached 220g, stop passing the gas, keep the temperature for 1h, cool, and remove the reaction liquid. It was filtered and rectified to obtain 596 g of 1,1,2,2-tetrafluoroethyl-2,2,3,3,4,4,5,5-octafluoropentyl ether with a yield of 90% and a purity of 99.8%.
synthesis of 1H,1H,5H-Octafluoropentyl 1,1,2,2-Tetrafluoroethyl Ether
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