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ChemicalBook--->CAS DataBase List--->156641-98-4

156641-98-4

156641-98-4 Structure

156641-98-4 Structure
IdentificationMore
[Name]

6-METHOXY-2-NAPHTHALENEBORONIC ACID
[CAS]

156641-98-4
[Synonyms]

6-METHOXY-2-NAPHTHALENEBORONIC ACID
(6-METHOXY-2-NAPHTHALENYL)BORONIC ACID
(6-METHOXY-2-NAPHTHYL)BORONIC ACID
6-METHOXYNAPHTHALENE-2-BORONIC ACID
6-METHOXYNAPHTHYL-2-BORONIC ACID
AKOS BRN-0219
CHEMBRDG-BB 4003299
6-Methoxy-2-Naphthaleneboronic
6-Methoxy-2-naphthaleneboronic acid ,97%
[EINECS(EC#)]

627-194-5
[Molecular Formula]

C11H11BO3
[MDL Number]

MFCD03093087
[Molecular Weight]

202.01
[MOL File]

156641-98-4.mol
Chemical PropertiesBack Directory
[Appearance]

White to off-white crystalline powder
[Melting point ]

>295 °C(lit.)
[Boiling point ]

416.2±37.0 °C(Predicted)
[density ]

1.23±0.1 g/cm3(Predicted)
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

DMSO (Slightly), Methanol (Slightly, Heated)
[form ]

powder to crystal
[pka]

8.72±0.30(Predicted)
[color ]

White to Orange to Green
[Detection Methods]

HPLC,NMR
[BRN ]

7636998
[CAS DataBase Reference]

156641-98-4(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HazardClass ]

IRRITANT
[HS Code ]

29163990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Tetrahydrofuran-->Nitrogen-->Dimethyl sulfate-->Triisopropyl borate-->6-Bromo-2-naphthol-->SEC-BUTYLLITHIUM
[Preparation Products]

6-Methoxy-2-vinylnaphthalene-->6-ETHYL-2-METHOXYLNAPHTHALINE-->3-(6-Methoxynaphthalen-2-yl)benzaldehyde
Hazard InformationBack Directory
[Chemical Properties]

White to off-white crystalline powder
[Uses]

Reactant for:
  • Suzuki-Miyaura coupling
  • Enantioselective a-arylation of carbonyls via copper-bisoxazoline catalysis
  • Enantioselective synthesis of aryl ketones
  • Copper-catalyzed trifluoromethylation
  • Rhodium-catalyzed oxidative coupling with alkynes
[Uses]

suzuki reaction
[General Description]

Contains varying amounts of anhydride.
Spectrum DetailBack Directory
[Spectrum Detail]

6-METHOXY-2-NAPHTHALENEBORONIC ACID(156641-98-4)IR
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

6-Methoxy-2-naphthaleneboronic acid, 95%(156641-98-4)
[Sigma Aldrich]

156641-98-4(sigmaaldrich)
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