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ChemicalBook--->CAS DataBase List--->156-43-4

156-43-4

156-43-4 Structure

156-43-4 Structure
IdentificationMore
[Name]

Phenetidine
[CAS]

156-43-4
[Synonyms]

1-AMINO-4-ETHOXYBENZENE
4-AMINOETHOXYBENZENE
4'-AMINOPHENETOL
4-AMINOPHENETOLE
4-ETHOXYANILINE
4-ETHOXYYANILINE
4-PHENETIDINE
AKOS BBS-00003550
P-ETHOXYANILINE
phenetidine
P-PHENETIDINE
4-ethoxy-benzenamin
4-Ethoxybenzenamine
4-ethoxy-Benzenamine
4-Ethoxybenzeneamine
Amino-phenyl ethyl ether
Aniline, p-ethoxy-
Benzenam
Benzenamine, 4-ethoxy-
benzenamine,4-ethoxy-
[EINECS(EC#)]

205-855-5
[Molecular Formula]

C8H11NO
[MDL Number]

MFCD00007865
[Molecular Weight]

137.18
[MOL File]

156-43-4.mol
Chemical PropertiesBack Directory
[Appearance]

colourless liquid
[Melting point ]

2-5 °C(lit.)
[Boiling point ]

250 °C(lit.)
[density ]

1.065 g/mL at 25 °C(lit.)
[vapor pressure ]

2.93Pa at 25℃
[refractive index ]

n20/D 1.559(lit.)
[Fp ]

240 °F
[storage temp. ]

2-8°C
[solubility ]

20g/l
[form ]

A liquid
[pka]

5.2(at 28℃)
[color ]

Clear Yellow
[PH]

8 (1g/l, H2O, 20℃)
[Stability:]

Stable, but light and air sensitive. Combustible. Incompatible with strong oxidizing agents.
[Water Solubility ]

practically insoluble
[Sensitive ]

Air Sensitive
[Merck ]

14,7228
[BRN ]

606666
[Dielectric constant]

7.3(21℃)
[InChIKey]

IMPPGHMHELILKG-UHFFFAOYSA-N
[CAS DataBase Reference]

156-43-4(CAS DataBase Reference)
[NIST Chemistry Reference]

4-Ethoxyaniline(156-43-4)
[EPA Substance Registry System]

156-43-4(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T,Xi,Xn
[Risk Statements ]

R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R33:Danger of cumulative effects.
R68:Possible risk of irreversible effects.
R43:May cause sensitization by skin contact.
R36:Irritating to the eyes.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S46:If swallowed, seek medical advice immediately and show this container or label .
[RIDADR ]

UN 2311 6.1/PG 3
[WGK Germany ]

1
[RTECS ]

SI6465500
[F ]

8-10
[Hazard Note ]

Irritant
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29222200
[Safety Profile]

Poison by inhalation. Moderately toxic by ingestion and intraperitoneal routes. Caution: It can be absorbed through the skin. A skin and eye irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx.
[Toxicity]

LD50 orl-rat: 580 mg/kg GISAAA 35(8),28,70
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Sodium hydroxide-->Methanol-->Sodium sulfide-->4-Chloronitrobenzene-->4-Aminophenol-->4-NITROPHENETOLE
[Preparation Products]

Acid Blue 90-->Phenacetin-->Acid Blue 83-->Ethoxyquin-->2-((4-ETHOXYPHENYL)AMINO)-4-NITROBENZOIC ACID-->H-GLU-LYS-OH-->Aethoxidum-->N-(4-Ethoxyphenyl)-3-hydroxy-2-naphthamide-->4-ETHOXYBENZONITRILE-->2-METHYL-6-ETHOXYQUINOLINE-->2-Amino-6-ethoxybenzothiazole-->Acid Blue 83-->Acid Blue 90-->N-(4-Ethoxyphenyl)-3-hydroxy-2-naphthamide-->Sulfanilamide, N4-(p-ethoxyphenyl)-3-nitro--->sodium hydrogen -2-ethoxy-5-[[4-[[4-[(4-ethoxy-3-sulphonatophenyl)amino]phenyl]-(1H-indol-3-yl-1-methyl-2-phenyl)methylene]-2,5-cyclohexadien-1-ylidene]amino]benzenesulphonate-->Solvent Red 3-->Mordant Yellow 38
Hazard InformationBack Directory
[General Description]

Colorless to dark red liquid.
[Reactivity Profile]

P-PHENETIDINE(156-43-4) reacts vigorously with powerful oxidizers.
[Air & Water Reactions]

Very sensitive to exposure to air and light. Turns red to brown on exposure to light and air. . Slightly soluble in water.
[Fire Hazard]

This compound is combustible.
[Chemical Properties]

colourless liquid
[Uses]

A toxic metabolite of Phenacetin (P294580) which exhibits high renal toxicity. p-Phenetidine also reduced COX-1 and COX-2 expression in neutrophils.
[Definition]

ChEBI: An aromatic ether that is aniline in which the hydrogen at position 4 is replaced by an ethoxy group. It is a hydrolysis metabolite of phenacetin.
[Synthesis Reference(s)]

Journal of Medicinal Chemistry, 27, p. 347, 1984 DOI: 10.1021/jm00369a019
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

4-Ethoxyaniline(156-43-4).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Phenetidine(156-43-4)MS
Phenetidine(156-43-4)1HNMR
Phenetidine(156-43-4)13CNMR
Phenetidine(156-43-4)IR1
Phenetidine(156-43-4)IR2
Phenetidine(156-43-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

p-Phenetidine, 98%(156-43-4)
[Alfa Aesar]

p-Phenetidine, 98%(156-43-4)
[Sigma Aldrich]

156-43-4(sigmaaldrich)
[TCI AMERICA]

p-Phenetidine,>98.0%(GC)(156-43-4)
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