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ChemicalBook--->CAS DataBase List--->148651-35-8

148651-35-8

148651-35-8 Structure

148651-35-8 Structure
IdentificationBack Directory
[Name]

2-CHLOROPHENYLZINC IODIDE
[CAS]

148651-35-8
[Synonyms]

2-CHLOROPHENYLZINC IODIDE
2-chlorophenylzinc iodide solution
2-Chlorophenylzinc iodide solution 0.5 in THF
2-Chlorophenylzinc iodide solution 0.5M in THF
2-Chlorophenylzinc iodide 0.5 M in Tetrahydrofuran
2-CHLOROPHENYLZINC IODIDE, 0.5M SOLUTION IN TETRAHYDROFURAN
2-Chlorophenylzinc iodide, Packaged under Argon in resealable ChemSeal? bottles
2-Chlorophenylzinc iodide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
[Molecular Formula]

C6H4ClIZn
[MDL Number]

MFCD01863648
[MOL File]

148651-35-8.mol
[Molecular Weight]

303.84
Chemical PropertiesBack Directory
[density ]

0.973 g/mL at 25 °C
[Fp ]

1 °F
[storage temp. ]

2-8°C
[Sensitive ]

Air & Light Sensitive
[Exposure limits]

ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
[CAS DataBase Reference]

148651-35-8
Safety DataBack Directory
[Symbol(GHS) ]


GHS05,GHS02,GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H261-H314-H318-H333-H225-H302-H319-H335-H351
[Precautionary statements ]

P223-P303+P361+P353-P405-P501a-P210-P280-P301+P312+P330-P305+P351+P338-P370+P378-P403+P235
[Hazard Codes ]

F,Xn
[Risk Statements ]

11-19-22-36/37/38-40-36/37
[Safety Statements ]

16-26-33-36-36/37
[RIDADR ]

UN 2056 3/PG 2
[WGK Germany ]

1
[HazardClass ]

4.3
Hazard InformationBack Directory
[Uses]

2-Chlorophenylzinc iodide is an organozinc compound, which can be used as a reactant in Negishi cross-coupling reaction to construct carbon-carbon bonds by reacting with organic halides using nickel or palladium catalysts.
It can also be utilized as a reactant to prepare:
  • Arylmethanes via rhodium-catalyzed cross-coupling reaction with methyl halides.
  • (2-chlorobenzyl)trimethylsilane by Rh-catalyzed cross-coupling reaction with (iodomethyl)trimethylsilane.
  • Dichloro biphenyl by palladium catalyzed oxidative homocoupling reaction using N-chlorosuccinimide (NCS) or O2 as the oxidant.

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